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Application of the Hole Group Quasi-Chemical Model to Evaluation of Azeotropic Properties

  • Physicochemical Studies of Systems and Processes
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Abstract

Azeotropic parameters (composition, boiling point, equilibrium pressure) were calculated in terms of the Viktorov-Smirnova lattice-hole quasi-chemical group model for binary and ternary systems in which there is no stratification of solutions formed by various components (hydrocarbons, alkanols, acetic acid, ethanoates, chloroform, acetone, pyridine, and water). Azeotropes of various kinds (positive, negative, saddle-type) were found using simple algorithms, including composition variation. Thirty binary, nine ternary, and one quaternary systems were considered. New group parameters were evaluated. The results of calculations of azeotropes were compared with published experimental data.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    I. V. Prikhodko & A. M. Chudakov

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  1. I. V. Prikhodko
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  2. A. M. Chudakov
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__________

Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 8, 2005, pp. 1258–1267.

Original Russian Text Copyright © 2005 by Prikhodko, Chudakov.

Reported at the XVI International Congress on Chemical Technology, CHISA2004, Prague, Czechia, August 22–26, 2004.

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Prikhodko, I.V., Chudakov, A.M. Application of the Hole Group Quasi-Chemical Model to Evaluation of Azeotropic Properties. Russ J Appl Chem 78, 1235–1244 (2005). https://doi.org/10.1007/s11167-005-0489-3

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  • DOI: https://doi.org/10.1007/s11167-005-0489-3

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