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Preparation of Branched Poly(Methyl Methacrylate) Using a Macroinitiator Based on Cobalt(II) 3-Allylpentane-2,4-dionate

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

Cobalt(II) 2-allylpentane-2,4-dionate, when used as an initiator of methyl methacrylate polymerization, yields a polymer containing metal chelate groups and exhibiting the properties of a macroinitiator capable of initiating secondary polymerization with the formation of branched high-molecular-weight methyl methacrylate polymers with a low polydispersity.

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Authors and Affiliations

  1. Mechnikov Odessa National University, Odessa, Ukraine

    O. V. Shevchenko, I. S. Voloshanovskii, E. V. Petrova & T. I. Berbat

Authors
  1. O. V. Shevchenko
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  2. I. S. Voloshanovskii
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  3. E. V. Petrova
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  4. T. I. Berbat
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Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 3, 2005, pp. 479–483.

Original Russian Text Copyright © 2005 by Shevchenko, Voloshanovskii, Petrova, Berbat.

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Shevchenko, O.V., Voloshanovskii, I.S., Petrova, E.V. et al. Preparation of Branched Poly(Methyl Methacrylate) Using a Macroinitiator Based on Cobalt(II) 3-Allylpentane-2,4-dionate. Russ J Appl Chem 78, 474–477 (2005). https://doi.org/10.1007/s11167-005-0321-0

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  • DOI: https://doi.org/10.1007/s11167-005-0321-0

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