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Mechanism of Depolymerization of Polymeric p-Dinitrosobenzene in Vulcanization of Unsaturated Rubbers: A Quantum-Chemical Study

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

The mechanism of depolymerization of polymeric p-dinitrosobenzene in vulcanization of unsaturated rubbers is analyzed. The results obtained explain why the vulcanizing activity of p-dinitrosobenzene decreases in the course of its prolonged storage.

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Authors and Affiliations

  1. Kazan State University of Power Engineering, Kazan, Tatarstan, Russia

    O. R. Klyuchnikov, D. V. Chachkov, R. Ya. Deberdeev & G. E. Zaikov

  2. Kazan State Technological University, Kazan, Tatarstan, Russia

    O. R. Klyuchnikov, D. V. Chachkov, R. Ya. Deberdeev & G. E. Zaikov

  3. Emanuel’ Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    O. R. Klyuchnikov, D. V. Chachkov, R. Ya. Deberdeev & G. E. Zaikov

Authors
  1. O. R. Klyuchnikov
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  2. D. V. Chachkov
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  3. R. Ya. Deberdeev
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  4. G. E. Zaikov
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__________

Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 2, 2005, pp. 320–323.

Original Russian Text Copyright © 2005 by Klyuchnikov, Chachkov, Deberdeev, Zaikov.

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Klyuchnikov, O.R., Chachkov, D.V., Deberdeev, R.Y. et al. Mechanism of Depolymerization of Polymeric p-Dinitrosobenzene in Vulcanization of Unsaturated Rubbers: A Quantum-Chemical Study. Russ J Appl Chem 78, 315–318 (2005). https://doi.org/10.1007/s11167-005-0282-3

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  • DOI: https://doi.org/10.1007/s11167-005-0282-3

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