Skip to main content
SpringerLink
Log in

Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Energetic metal complexes, pentammine(cyclopentamethylenetetrazole)cobalt(III) perchlorate and tetraammine-bis(cyclopentamethylenetetrazole)cobalt(III) perchlorate, were obtained by reaction of aquapentaamminecobalt(III) and diaquatetraamminecobalt(III) ions with cyclopentamethylenetetrazole. Microwave heating was used, together with the conventional convective heating, for thermal activation of the process. The thermal decomposition of the compounds synthesized was studied. The explosive characteristics and toxicity of the metal complexes were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Zhoui, S., Liu, J., and Xie, G., Theory and Practice of Energetic Materials, Huang, P., Li, S., and Wang, Y., Eds., New York: Sci. Press, 2003, vol. 5, part A, pp. 183–185.

    Google Scholar 

  2. Danilov, Yu.N., Ilyushin, M.A., and Tselinskii, I.V., Promyshlennye vzryvchatye veshchestva. Chast’ 1. Initsiiruyushchie vzryvchatye veshchestva. Tekst lektsii (Industrial Explosives, part 1, Priming Explosives: Course of Lectures), St. Petersburg: IK Sintez, 2004.

    Google Scholar 

  3. Ilyushin, M.A., Tselinsky, I.V., Zhilin, A.Yu., et. al., Hunneng Cailiao-Energ. Mater., 2004, vol. 12, no.1, pp. 15–19.

    CAS  Google Scholar 

  4. Grushko, Ya.M., Vrednye neorganicheskie soedineniya v promyshlennykh stochnykh vodakh (Noxious Inorganic Substances in Industrial Wastewater), Moscow: Khimiya, 1989.

    Google Scholar 

  5. Bespamyatnov, G.P. and Krotov, Yu.A., Predel’nodopustimye kontsentratsii khimicheskikh veshchestv v okruzhayushchei srede (Maximum Permissible Concentrations of Chemical Substances in the Environment), Leningrad: Khimiya. 1985.

    Google Scholar 

  6. Soldatenkov, A.T., Kolyadina, N.M., and Shendrik, I.V., Osnovy organicheskoi khimii lekarstvennykh veshchestv (Fundamentals of the Organic Chemistry of Pharmaceutical Substances), Moscow: Khimiya, 2001.

    Google Scholar 

  7. Zhilin, A.Yu., Ilyushin, M.A., and Tselinskii, I.V., Zh. Obshch. Khim., 2001, vol. 71, no.5, pp. 710–713.

    Google Scholar 

  8. Zhilin, A.Yu., Ilyushin, M.A., Tselinskii, I.V., and Brykov, A.S., Zh. Prikl. Khim., 2001, vol. 74, no.1, pp. 96–99.

    Google Scholar 

  9. Fronabarger, J., Schuman, A., Chapman, R.D., et al., Am. Inst. Aeronautics Astronautics Pap., 1995, no. 2858, pp. 1–7.

  10. Moore, D.S. and Robinson, S.D., Adv. Inorg. Chem., 1988, vol. 32, pp. 171–239.

    CAS  Google Scholar 

  11. Bramley, R., Brorson, M., Sargeson, A.M., and Schaffer, C.E., J. Am. Chem. Soc., 1985, vol. 107, no.9, pp. 2780–2787.

    CAS  Google Scholar 

  12. Sheng, D., Ma, F., Sun, F., and Lu, Q., Hanneng Cailiao-Energ. Mater., 2000, vol. 8, no.3, pp. 100–103.

    CAS  Google Scholar 

  13. Moore, D.S. and Robinson, S.D., Adv. Inorg. Chem., 1988, vol. 32, pp. 171–239.

    CAS  Google Scholar 

  14. Zhilin, A.Yu., Ilyushin, M.A., Tselinskii, I.V., et al., Zh. Prikl. Khim., 2002, vol. 75, no.11, pp. 1885–1888.

    Google Scholar 

  15. Comprehensive Chemical Kinetics, Bamford, C.H. and Tipper, C.F.H., Eds., vol. 22, Reactions in the Solid State, Brown, M.E., Dollimore, D., and Galwey, A.K., Eds., Amsterdam: Elsevier, 1980.

    Google Scholar 

  16. Ilyushin, M.A., Kotomin, A.A., Dushenok, S.A., et al., Sbornik nauchnykh trudov NPO im. S.A. Lavochkina (Coll. Sci. Works, Lavochkin Research-and-Production Association), 2002, no. 4, pp. 87–96.

  17. Avanesov, D.S., Praktikum po fiziko-khimicheskim ispytaniyam vzryvchatykh veshchestv (Manual of Physicochemical Tests of Explosives), Moscow: GIOP, 1959.

    Google Scholar 

  18. Novakovskii, M.S., Laboratornye raboty po khimii kompleksnykh soedinenii (Laboratory Practical Work on Chemistry of Complex Compounds), Kharkov: Kharkov Gos. Univ., 1972.

    Google Scholar 

  19. Generalov, M.B., Osnovnye protsessy i apparaty tekhnologii promyshlennykh vzryvchatykh veshchestv (Basic Processes and Apparatus in Technology of Industrial Explosives), Moscow: Akademkniga, 2004, p. 381.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), St. Petersburg, Russia

    A. Yu. Zhilin, M. A. Ilyushin, I. V. Tselinskii, Yu. A. Nikitina, A. S. Kozlov & I. V. Shugalei

Authors
  1. A. Yu. Zhilin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Ilyushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Tselinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. A. Nikitina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. S. Kozlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. V. Shugalei
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 2, 2005, pp. 195–199.

Original Russian Text Copyright © 2005 by Zhilin, Ilyushin, Tselinskii, Nikitina, Kozlov, Shugalei.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhilin, A.Y., Ilyushin, M.A., Tselinskii, I.V. et al. Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand. Russ J Appl Chem 78, 188–192 (2005). https://doi.org/10.1007/s11167-005-0256-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11167-005-0256-5

Keywords

Search

Navigation