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Thermocatalytic decomposition of 1-methylcyclohexyl hydroperoxide

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Abstract

A mathematical model of a multistage process of thermocatalytic decomposition of 1-methyl-cyclohexyl hydroperoxide in the presence of sodium stearate is developed. A procedure for calculating the unknown rate and equilibrium constants of the elementary and overall reaction stages is described. It is based on an analysis of the kinetic relationships in consumption of the initial products and accumulation of the intermediate and final products of thermocatalytic decomposition, with account of the known constants for individual stages.

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REFERENCES

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, St. Petersburg, Russia

    A. M. Syroezhko & O. Yu. Begak

  2. Mendeleev Russian Research Institute of Metrology, Federal State Unitary Enterprise, St. Petersburg, Russia

    A. M. Syroezhko & O. Yu. Begak

Authors
  1. A. M. Syroezhko
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  2. O. Yu. Begak
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Additional information

Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 12, 2004, pp. 2003–2010.

Original Russian Text Copyright © 2004 by Syroezhko, Begak.

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Syroezhko, A.M., Begak, O.Y. Thermocatalytic decomposition of 1-methylcyclohexyl hydroperoxide. Russ J Appl Chem 77, 1979–1986 (2004). https://doi.org/10.1007/s11167-005-0204-4

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  • DOI: https://doi.org/10.1007/s11167-005-0204-4

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