Skip to main content
Log in

Surface structure and thermal oxidative degradation of the reaction products of polyethylene with PCl3 and VOCl3 vapors

  • Macromolecular Chemistry and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Reaction products of phosphorus(III) chloride and vanadium(V) oxychloride with low-density polyethylene were studied by chemical analysis and physicochemical (IR spectroscopy and atomic-force microscopy) methods. Thermaloxidative transformations of the initial and modified samples were studied by differential thermal analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Povstugar, V.I., Kodolov, V.I., and Mikhailova, S.S., Stroenie i svoistva poverkhnosti polimernykh materialov (Structure and Properties of the Surface of Polymeric Materials), Moscow: Khimiya, 1988.

    Google Scholar 

  2. Grassie, N. and Scott, G., Polymer Degradation and Stabilisation, London: Cambridge Univ. Press, 1985.

    Google Scholar 

  3. Malygin, A.A., Zh. Prikl. Khim., 1996, vol. 69, no.10, pp. 1585–1593.

    Google Scholar 

  4. Sirota, A.G., Modifikatsiya struktury i svoistv poliolefinov (Modification of the Structure and Properties of Polyolefins), Leningrad: Khimiya, 1984.

    Google Scholar 

  5. Magonov, S.N., Vysokomol. Soedin., Ser. B, 1996, vol. 38, no.1, pp. 143–182.

    Google Scholar 

  6. Trifonov, S.A. and Malygin, A.A., Zh. Obshch. Khim., 1998, vol. 68, no.12, pp. 1994–1998.

    Google Scholar 

  7. Trifonov, S.A., Lapikov, V.A., and Malygin, A.A., Vliyanie khimicheskogo modifitsirovaniya khloridom fosfora(III) poverkhnosti polietilena na ego termookislitel’nuyu stoikost’ (Influence of Chemical Modification with Phopshorus(III) Chloride of the Polyethylene Surface on Its Resistance to Thermal Oxidation), Available from VINITI RAS, February 26, 2002, no. 374–V2 002.

  8. Trifonov, S.A., Semenova, E.Yu., and Malygin, A.A., Zh. Prikl. Khim., 1996, vol. 69, no.11, pp. 1917–1920.

    Google Scholar 

  9. Kazitsyna, L.A. and Kupletskaya, N.V., Primenenie UF-, IK-, YaMR i mass-spektroskopii v organicheskoi khimii (Application of UV, IR, NMR, and Mass Spectroscopy to Organic Chemistry), Moscow: Mosk. Gos. Univ., 1979.

    Google Scholar 

  10. Van Wazer, I.R., Phosphorus and Its Compounds, New York: Wiley-Interscience, 1958, vol. 1.

    Google Scholar 

  11. Bryk, M.T., Destruktisya napolnennykh polimerov (Degradation of Filled Polymers), Moscow: Khimiya, 1989.

    Google Scholar 

  12. Trifonov, S.A., Malygin, A.A., and Gnatyuk, S.P., Plast. Massy, 1988, no. 7, pp. 35–36.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 11, 2004, pp. 1872–1876.

Original Russian Text Copyright © 2004 by Trifonov, Sosnov, Malygin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Trifonov, S.A., Sosnov, E.A. & Malygin, A.A. Surface structure and thermal oxidative degradation of the reaction products of polyethylene with PCl3 and VOCl3 vapors. Russ J Appl Chem 77, 1854–1858 (2004). https://doi.org/10.1007/s11167-005-0175-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11167-005-0175-5

Keywords

Navigation