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Nano-SiO2@nPr@DPyE-Ni: a novel nanocatalyst for the rapid production of symmetric di-aryl sulfides and pyrazolones

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Abstract

Initially, a new organometallic catalyst with nano-silica gel substrate and Ni active center, namely nano-SiO2@nPr@DPyE-Ni was produced, and its properties were thoroughly debated. It was then applied with excellent performance to produce symmetric di-aryl sulfides (14 entries, 78–98%, 20–150 min, EtOH, and 70 °C), and 2-aryl-5-methyl-2,3-dihydro-1H-3-pyrazolones (12 entries, 91–98%, 2–4 min, solvent-free, and r.t). In both production routes, the nanocatalyst was recyclable and reusable for more than seven runs, and its heterogeneous nature was checked and confirmed through the recycling results, hot filtration test, and ICP-OES (coupled plasma optical emission spectroscopy) method.

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Acknowledgments

The authors are grateful to acknowledge the Takin Shimi Sepanta Industries Co, Ilam, Iran.

Funding

The authors have no relevant financial or non-financial interests to disclose.

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Islamic University of Madinah, Madinah, Saudi Arabia

    Hamad AlMohamadi

  2. Escuela de Ingeniería Civil, Universidad César Vallejo, Chimbote, Peru

    Carlos Rodriguez-Benites

  3. Department of Biotechnology and Genetics, Jain (Deemed-to-Be) University, Bengaluru, Karnataka, 560069, India

    Pooja Bansal

  4. Department of Allied Healthcare and Sciences, Vivekananda Global University, Jaipur, Rajasthan, 303012, India

    Pooja Bansal

  5. Medical Laboratory Technique College, The Islamic University, Najaf, Iraq

    Ahmed Huseen Redhee

  6. Medical Laboratory Technique College, The Islamic University of Al Diwaniyah, Al Diwaniyah, Iraq

    Ahmed Huseen Redhee

  7. Medical Laboratory Technique College, The Islamic University of Babylon, Babylon, Iraq

    Ahmed Huseen Redhee

  8. Institute of Pharmacy Named After A.P. Nelyubin, Sechenov First Moscow State Medical University, 8 Trubetskaya St., Bldg. 2, Moscow, 119991, Russia

    Dmitry Olegovich Bokov

  9. Laboratory of Food Chemistry, Federal Research Center of Nutrition, Biotechnology and Food Safety, 2/14 Ustyinsky Pr, Moscow, 109240, Russia

    Dmitry Olegovich Bokov

  10. Department of Petroleum Engineering, Al-Kitab University, Altun Kupri, Iraq

    Ameer H. Al-Rubaye

  11. Immunology and Physiology College of Health and Medical Technology, Al-Ayen University, Thi-Qar, Nasiriyah, 64001, Iraq

    Maytham T. Qasim

  12. Department of Nuclear and Renewable Energy, Ural Federal University Named After the First President of Russia Boris Yeltsin, Ekaterinburg, 620002, Russia

    Abhinav Kumar

  13. Department of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul, 41001, Iraq

    Yasser Fakri Mustafa

  14. Sirvan Industrial Zone, Takin Shimi Sepanta Industries Co, Ilam, PO 6958140120, Iran

    Maryam Sadat Ghorayshi Nejad

Authors
  1. Hamad AlMohamadi
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  2. Carlos Rodriguez-Benites
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  3. Pooja Bansal
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  4. Ahmed Huseen Redhee
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  5. Dmitry Olegovich Bokov
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  10. Maryam Sadat Ghorayshi Nejad
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Contributions

H.A synthesized several di-aryl sulfide derivatives (1a–7a) and edited the paper. C.R.B synthesized several pyrazolone derivatives (1b–6b) and designed the graphical abstract. P.B synthesized several di-aryl sulfide derivatives (8a–14a). A.H.R synthesized several di-aryl sulfides derivatives (7b–12b). B.D.O optimized reaction conditions for the preparation of pyrazolone derivatives. A.H.A optimized reaction conditions for the preparation of di-aryl sulfides. M.T.Q characterized the skeleton of the catalyst via HRTEM, FESEM, and XRD analyses. A.K characterized the skeleton of the catalyst by ICP, EDS, and elemental mapping analyses. Y.F.M characterized the skeleton of the catalyst through TGA, FTIR, and BET analyses. M.S.G.N fabricated the catalyst and wrote the paper.

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Correspondence to Maryam Sadat Ghorayshi Nejad.

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AlMohamadi, H., Rodriguez-Benites, C., Bansal, P. et al. Nano-SiO2@nPr@DPyE-Ni: a novel nanocatalyst for the rapid production of symmetric di-aryl sulfides and pyrazolones. Res Chem Intermed (2024). https://doi.org/10.1007/s11164-024-05296-4

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