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Boosting lithium storage of BaFe12O19 by element doping engineering

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Abstract

Ternary metal oxides have been considered a promising anode material for lithium-ion batteries (LIBs) based on their stable chemical compositions and abundant active sites. This work doped Mn into BaFe12O19 by a simple hydrothermal method and subsequent annealing treatment. By adjusting the ratio of raw materials, we obtained a Mn-doped BaFe12O19 electrode with an irregular hexagonal morphology. The doped Mn ions are in  + 2, + 3, and + 4 valence states. Due to the octahedral position preference, Mn2+ tends to occupy the tetrahedral position. At the same time, Mn4+ favors octahedral coordination, and most Mn resides in (distorted) octahedral coordination in the form of + 3 valence state. Employed as a LIB anode, the specific capacity of the electrode reached 782.57 mA h g−1 after 150 cycles at a current density of 100 mA g−1. Even at a high current of 1 A g−1, the specific capacity remained at 439.99 mA h g−1 after 450 cycles. Mn-doped BaFe12O19 exhibited better cycling stability and electrochemical performance compared with pure BaFe12O19, which may be attributed to significantly enhanced charge transport kinetics at the interface between electrodes and electrolytes by Mn doping.

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Acknowledgements

This work was supported by the Shenyang University of Technology (QNPY202209-4) and the Education Department of Liaoning Province (JYTQN2023285).

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Authors and Affiliations

  1. School of Environmental and Chemical Engineering, Shenyang University of Technology, Shenyang, 110870, China

    Mingyuan Ye, Yuhan Wu, Ziqi Zhao, Jiaqi Lv, Yu-Hang Zhang, Peng-Fei Wang, Li Liu & Fa-Nian Shi

  2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, China

    Yuhan Wu

  3. College of Materials Science and Engineering, Nanjing Tech University, Nanjing, China

    Xiaorui Hao

  4. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang, China

    Liying Liu

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  1. Mingyuan Ye
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Contributions

MY: Carried out material synthesis, characterizations, and electrochemical measurements and drafted the manuscript. YW: Provided design conceptualization and financial support, reviewed and edited the manuscript draft XH and ZZ: Carried out electrochemical measurements LL and JL: Carried out material characterizations YHZ: Formal analyzed and reviewed the manuscript draft PFW: Curated data and edited the manuscript draft LL: Reviewed and edited the manuscript draft FNS: Provided design conceptualization and financial support, reviewed and edited the manuscript draft

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Correspondence to Yuhan Wu, Li Liu or Fa-Nian Shi.

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Ye, M., Wu, Y., Hao, X. et al. Boosting lithium storage of BaFe12O19 by element doping engineering. Res Chem Intermed 50, 2395–2408 (2024). https://doi.org/10.1007/s11164-024-05263-z

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