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Fabrication of Co/HMS catalyst by modulating the hydrothermal time for the oxidative dehydrogenation of C2H6 with CO2 to C2H4

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Abstract

A series of cobalt doped hexagonal mesoporous silica (Co-HMS) with the different hydrothermal time was prepared by direct hydrothermal method and applied for oxidative dehydrogenation (ODH) reaction of ethane with carbon dioxide. Structural and chemical properties of the catalysts were characterized by nitrogen adsorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), electron dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and Raman and ultraviolet–visible (UV–vis) spectroscopy. These characterizations showed that cobalt not only entered the framework of Co-HMS catalysts but also was evenly dispersed in the bulk. The valence state and coordination mode of cobalt played an important role in the whole ODH reaction system of ethane with carbon dioxide. 1%Co-HMS (1 h) with dominant Co2+ had the highest conversion of ethane (26.0%). The formation of tetrahedral coordination Co2+(Td) is beneficial to the breaking of ethane hydrocarbon bond and the improvement of ethylene selectivity. 1%Co-HMS (1 h) with more Co2+(Td) performed the highest ethylene selectivity of 92.6%, which was stable during the 10 h reaction time.

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Acknowledgements

Financial support was provided by the Haihe Laboratory of Sustainable Chemical Transformations.

Funding

Financial support was provided by the Haihe Laboratory of Sustainable Chemical Transformations.

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin, 300072, China

    Mianjing Li, Feigang Zhao, Pengfei Zhang, Dan Guo, Fei Xiao & Shengping Wang

  2. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300192, China

    Mianjing Li, Feigang Zhao, Pengfei Zhang, Dan Guo, Fei Xiao & Shengping Wang

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  1. Mianjing Li
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  2. Feigang Zhao
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  3. Pengfei Zhang
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Contributions

Mianjing Li was contributed to conceptualization, methodology, investigation, validation, data curation, formal analysis, writing–original draft; Fei Xiao was contributed to conceptualization, methodology, investigation, validation, data curation, formal analysis; Feigang Zhao was contributed to investigation, formal analysis; Dan Guo was contributed to investigation, formal analysis; Pengfei Zhang was contributed to formal analysis; Shengping Wang was contributed to conceptualization, methodology, resources, writing—review and editing, supervision, funding acquisition, project administration.

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Correspondence to Shengping Wang.

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Li, M., Zhao, F., Zhang, P. et al. Fabrication of Co/HMS catalyst by modulating the hydrothermal time for the oxidative dehydrogenation of C2H6 with CO2 to C2H4. Res Chem Intermed 49, 3079–3096 (2023). https://doi.org/10.1007/s11164-023-05033-3

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