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Synergistic and efficient degradation of acid red 73 by using UV, H2O2, and PDS under neutral conditions: water matrix effects and transformation pathways

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Abstract

Dye wastewater with high concentration, large molecular weight, complex structure, and certain toxicity has brought a serious burden to the environment. In this study, acid red 73 dye (AR73) was used as the model pollutant to compare the degradation effects of different systems on AR73. The influence factors of a UV/hydrogen peroxide/peroxydisulfate (UV/H2O2/PDS) composite system, such as H2O2 dosage, initial concentration of AR73, initial pH value, anion concentration, and actual water, on the degradation of AR73 were investigated. Compared with other systems, the UV/H2O2/PDS composite system had the best degradation effect of AR73, with a degradation efficiency of 98.98%, which conforms to the pseudo-first-order reaction kinetic model, the pseudo-first-order reaction kinetic constant (kobs) is 0.1339 min−1. And the synergy coefficients in this complex system were all greater than 2. Specifically, the degradation efficiency of the UV/H2O2/PDS composite system for AR73 was the highest when the initial pH was neutral. The presence of anions inhibited the degradation of AR73, and the real water reduced the degradation efficiency for AR73. Electron spin resonance (ESR) detection and free radicals capture test demonstrated that hydroxyl radical (·OH) was the main reactive species in AR73 degradation, and its 80.66–84.93% contribution. With the destruction of the structure of AR73 by free radicals, anilines, phenols, and oxalic acid were found to be the main intermediate products during the degradation of AR73 by gas-phase mass spectrometry and UV–vis spectrograms. The changes in toxicity during the degradation of AR73 by the UV/H2O2/PDS complex system were also assessed.

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Acknowledgements

Our work was supported by the National Natural Science Foundation of China (Grant No. 51778267), the National Water Pollution Control and Treatment Science and Technology Major Project (No. 2012ZX07408001), the Jilin Province Science and Technology Department Project (No. 20190201113JC), the Jilin Provincial Department of Ecology and Environment Project (No.2019-15).

Funding

This study was funded by the National Natural Science Foundation of China (Grant No. 51778267); the National Water Pollution Control and Treatment Science and Technology Major Project (No. 2012ZX07408001); the Jilin Province Science and Technology Department Project (No. 20190201113JC); and the Jilin Provincial Department of Ecology and Environment Project (No.2019–15).

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Authors and Affiliations

  1. School of Municipal and Environmental Engineering, Jilin Jianzhu University, Changchun, 130118, China

    Yingzi Lin, Ao Hou, Hao Li, Chunyan Shi, Lei Chen, Baoling Yuan, Yi Liu, Yu Wang & Xiaochen Liu

  2. Key Laboratory of Songliao Aquatic Environment, Ministry of Education, Jilin Jianzhu University, Changchun, 130118, China

    Yingzi Lin

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  1. Yingzi Lin
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  2. Ao Hou
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  3. Hao Li
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  4. Chunyan Shi
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  5. Lei Chen
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  6. Baoling Yuan
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  7. Yi Liu
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  8. Yu Wang
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  9. Xiaochen Liu
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Contributions

YL involved in methodology, writing—review, and funding acquisition. AH involved in formal analysis, writing—original draft, and editing. HL involved in writing—original draft and data curation. CS involved in conceptualization. Lei Chen involved in supervision. BY involved in formal analysis. Yi Liu involved in project administration and supervision. YW involved in conceptualization. XL involved in writing— review and editing.

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Correspondence to Yingzi Lin.

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Lin, Y., Hou, A., Li, H. et al. Synergistic and efficient degradation of acid red 73 by using UV, H2O2, and PDS under neutral conditions: water matrix effects and transformation pathways. Res Chem Intermed 49, 23–42 (2023). https://doi.org/10.1007/s11164-022-04870-y

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