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Sono- and mechanochemical doping of tin dioxide with silver and its physicochemical characteristics and photocatalytic properties

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Abstract

Mechano- and sonochemical treatments were proposed as facile procedures for doping of precipitated SnO2 with silver. All obtained samples have been studied using XRD, SEM and EDS, XPS, adsorption–desorption of nitrogen, UV–Vis spectroscopy and potentiometric titration. XRD and SEM–EDS data showed that silver was uniformly distributed at surface of SnO2. The doped samples have a developed meso–macroporous structure. Narrowing the band gap and increasing in absorption of visible light result in high photocatalytic activity of doped SnO2 in the degradation of dyes and 4-clorophenol under visible irradiation. Relationship between physicochemical and photocatalytic properties of prepared samples has been discussed.

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SK contributed to the investigation and writing—original draft. MS was involved in the investigation, formal analysis and methodology. OK contributed to the investigation. VS contributed to the conceptualization, supervision and writing—review and editing. VS helped in the investigation. BC and ES contributed to the investigation.

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Correspondence to Svitlana Khalameida.

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Khalameida, S., Samsonenko, M., Khyzhun, O. et al. Sono- and mechanochemical doping of tin dioxide with silver and its physicochemical characteristics and photocatalytic properties. Res Chem Intermed 49, 121–145 (2023). https://doi.org/10.1007/s11164-022-04865-9

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