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Catalytic influence of mesoporous SBA-16 supported manganese molybdate on liquid phase selective oxidation of salicyl alcohol

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Abstract

Selective oxidation of alcohol to the corresponding aldehyde plays a pivotal role in organic synthesis. In the present study, 3D cubic cage-like mesoporous SBA-16 was synthesized by a one-pot hydrothermal route. Then SBA-16 supported MnMoO4 catalysts, designated as MnMoO4 (1, 3, and 5wt.%)/SBA-16, were prepared by the wet impregnation method. The catalysts were thoroughly characterized by various analytical techniques to verify phase purity, mesoporous structure, morphology, and oxidation state of the catalytic active sites. Further, catalytic activity was performed for the liquid phase oxidation of salicyl alcohol and its family members to obtain the respective aldehydes between 50 and 90 °C. MnMoO4 (3 wt.%)/SBA-16 showed higher catalytic activity than other catalysts by giving 88% salicyl alcohol conversion with 81% salicylaldehyde selectivity. The recovered catalyst retained activity for five cycles, thus proving MnMoO4 (3 wt.%)/SBA-16 is a better choice for commercial production of salicylaldehyde.

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References

  1. C.R. Lhermitte, K. Sivula, ACS Catal. 9, 3 (2019)

    Article  Google Scholar 

  2. X.-Q. Wu, X.-W. Wu, J.-S. Shen, H.-W. Zhang, RSC Adv. 4, 90 (2014)

    CAS  Google Scholar 

  3. Hu. Chao, K. Farshadfar, M.C. Dietl, A. Cervantes-Reyes, T. Wang, T. Adak, M. Rudolph, F. Rominger, J. Li, A. Alireza Ariafard, S.K. Hashmi, ACS Catal. 11(11), 6510 (2021)

    Article  Google Scholar 

  4. J. He, J. Zheng, J. Liu, X. She, X. Pan, Org. Lett. 8, 20 (2006)

    Google Scholar 

  5. N. Yoshida, K. Ogasawara, Org. Lett. 2(10), 1461 (2000)

    Article  CAS  Google Scholar 

  6. H.Y. Choi, E. Srisook, K.S. Jang, D.Y. Chi, J. Org. Chem. 70, 4 (2005)

    Google Scholar 

  7. L.M. Correia, M.M. Soliman, C.M. Granadeiro, S.S. Balula, L.M. Martins, A.J. Pombeiro, E.C. Alegria, Micropor. Mesopor. Mater. 320, 111111 (2021)

    Article  CAS  Google Scholar 

  8. C. Milone, R. Ingoglia, G. Neri, A. Pistone, S. Galvagno, Appl. Catal. A- Gen. 211, 2 (2001)

    Article  Google Scholar 

  9. L. Torrente-Murciano, T. Villager, D. Chadwick, ChemCatChem 7, 6 (2015)

    Article  Google Scholar 

  10. Y. Chen, H. Lim, Q. Tang, Y. Gao, T. Sun, Q. Yan, Y. Yang, Appl. Catal. A- Gen. 380, 1–2 (2010)

    Article  Google Scholar 

  11. C.A. Akinnawo, N. Bingwa, R. Meijboom, Catal. Commun. 145, 106115 (2020)

    Article  CAS  Google Scholar 

  12. F. Wang, J. Xu and S.-J. Liao, Chem. Commun. 6 (2002)

  13. Y. Pérez, R. Ballesteros, M. Fajardo, I. Sierra, I. del Hierro, J. Mol. Catal. A: Chem. 352, 45 (2012)

    Article  Google Scholar 

  14. S. Endud, K.-L. Wong, Micropor. Mesopor. Mater. 101, 1 (2007)

    Article  Google Scholar 

  15. D. Mousavi, M.H. Ardakani, S. Saeednia, M. Sabet, Res. Chem. Intermed. 47, 3 (2021)

    Article  Google Scholar 

  16. Y. Chen, Z. Guo, T. Chen, Y. Yang, J. Catal. 275, 1 (2010)

    Article  Google Scholar 

  17. V. Mahdavi, M. Mardani, Mater. Chem. Phys. 155, 136 (2015)

    Article  CAS  Google Scholar 

  18. X. Fu, S. Wu, Z. Li, X. Yang, X. Wang, L. Peng, J. Hu, Q. Huo, J. Guan, Q. Kan, RSC Adv. 6, 62 (2016)

    Google Scholar 

  19. D.D. Mal, S. Khilari, D. Pradhan, Green Chem. 20, 10 (2018)

    Article  Google Scholar 

  20. X. Li, T. Lunkenbein, J. Kröhnert, V. Pfeifer, F. Girgsdies, F. Rosowski, R. Schlögl, A. Trunschke, Faraday Discuss. 188, 99 (2016)

    Article  CAS  Google Scholar 

  21. S. Manimaran, K. Subramanian, R. Tschentscher, A. Pandurangan, J. Porous Mater. 29(2), 357 (2022)

    Article  CAS  Google Scholar 

  22. F. Namvar, F. Beshkar, M. Salavati-Niasari, J. Mater. Sci. Mater. Electron. 28, 11 (2017)

    Article  Google Scholar 

  23. F. Trifiro, C. Banfi, G. Caputo, P. Forzatti, I. Pasquon, J. Catal. 30, 3 (1973)

    Article  Google Scholar 

  24. H. Shoukat, A.A. Altaf, M. Hamayun, S. Ullah, S. Kausar, M. Hamza, S. Muhammad, A. Badshah, N. Rasool, M. Imran, ACS Omega 6, 30 (2021)

    Article  Google Scholar 

  25. J.M.R. Gallo, C. Bisio, L. Marchese, H.O. Pastore, Micropor. Mesopor. Mater. 145, 1 (2011)

    Article  Google Scholar 

  26. G.S.B. Bottazzi, M.L. Martínez, M.B.G. Costa, O.A. Anunziata, A.R. Beltramone, Appl. Catal. A- Gen. 404, 1 (2011)

    Google Scholar 

  27. C. Sekar, R. Kalai Selvan, S.T. Senthilkumar, B. Senthilkumar, C. Sanjeeviraja, Powder Technol. 215–216, 98 (2012)

    Article  CAS  Google Scholar 

  28. B. Saravanakumar, S.P. Ramachandran, G. Ravi, V. Ganesh, A. Sakunthala, R. Yuvakkumar, Appl. Phys. A 125(1), 1 (2019)

    Article  CAS  Google Scholar 

  29. S.N. Azizi, S. Ghasemi, A. Samadi-Maybodi, M. Ranjbar-Azad, Sens. Actuators B: Chem. 216, 271 (2015)

    Article  CAS  Google Scholar 

  30. X. Yan, L. Tian, J. Murowchick, X. Chen, J. Mater. Chem. A. 4, 10 (2016)

    Google Scholar 

  31. S. Yurdakal, M. Bellardita, I. Pibiri, L. Palmisano, V. Loddo, Catal. Today 380, 16 (2021)

    Article  CAS  Google Scholar 

  32. S.A. Carabineiro, Front. Chem. 7, 702 (2019)

    Article  CAS  Google Scholar 

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Acknowledgements

One of the authors, S.Manimaran gratefully acknowledges the Anna Centenary Research Fellowship (ACRF) funded by Anna University, Chennai for the financial support to carry out this work. The authors are thankful to the DST-FIST-sponsored Department of Chemistry, Anna University for providing the laboratory and instrumentation facilities.

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Authors and Affiliations

  1. Department of Chemistry, Anna University, Chennai, Tamil Nadu, 600 025, India

    Shanmugam Manimaran & Arumugam Pandurangan

  2. Department of Process Technology, SINTEF Industry, Oslo, Norway

    Roman Tschentscher

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  1. Shanmugam Manimaran
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  2. Roman Tschentscher
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  3. Arumugam Pandurangan
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Correspondence to Arumugam Pandurangan.

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Manimaran, S., Tschentscher, R. & Pandurangan, A. Catalytic influence of mesoporous SBA-16 supported manganese molybdate on liquid phase selective oxidation of salicyl alcohol. Res Chem Intermed 48, 3721–3737 (2022). https://doi.org/10.1007/s11164-022-04787-6

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