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Effects of partial substitution of Cu by Mn and Co in LaCu0.5Ni0.5O3 catalyst synthesized by mechanochemical method in the total oxidation of methane

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Abstract

This study pertains to the effects of Cu substitution by Mn and Co on the textural properties and catalytic activity of the LaCu0.5-xMnxNi0.5O3 (x= 0, 0.1, 0.3) and LaCu0.4Co0.1Ni0.5O3 catalysts for methane catalytic combustion. The perovskite catalysts were prepared by a solvent-free mechanochemical synthesis method. The catalytic results showed that adding Mn into the structure of LaCu0.5Ni0.5O3 improved the catalytic activity and thermal stability and also increased the specific surface area, whereas the addition of Co=0.1 led to a slight decrease in catalytic performance and specific surface area. The H2-TPR results illustrated that the substitution of Mn improved the reducibility feature of the catalysts. Among all the samples, LaCu0.2Mn0.3Ni0.5O3 catalyst exhibited the highest catalytic activity. The combustion of methane is a type of interfacial reaction, and considering the Mars–Van Krevelen mechanism, the increase in the catalytic activity can be related to the increment of lattice oxygen mobility and oxygen vacancy. Moreover, the decrease in calcination temperature of the LaCu0.2Mn0.3Ni0.5O3 improved the catalytic activity due to the increase in the BET area and the concentration of oxygen vacancy.

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References

  1. T.M. Onn, S. Zhang, L. Arroyo-Ramirez, Y.C. Chung, G.W. Graham, X. Pan, R.J. Gorte, ACS Catal. 5(10), 5596 (2015)

    Article  CAS  Google Scholar 

  2. F.F. Tao, J.J. Shan, L. Nguyen, Z. Wang, S. Zhang, L. Zhang, Z. Wu, W. Huang, S. Zeng, P. Hu, Nat. Commun. 6(1), 1 (2015)

    Article  CAS  Google Scholar 

  3. H. Peng, C. Rao, N. Zhang, X. Wang, W. Liu, W. Mao, L. Han, P. Zhang, S. Dai, Angew. Chem. 130(29), 9091 (2018)

    Article  Google Scholar 

  4. G. Ercolino, P. Stelmachowski, G. Grzybek, A. Kotarba, S. Specchia, Appl. Catal. B: Environ. 206, 712 (2017)

    Article  CAS  Google Scholar 

  5. X. Zou, R. Zebao Rui, H. Ji, ACS Catal. 7(3), 1615 (2017)

  6. S. Ojala, N. Koivikko, T. Laitinen, A. Mouammine, P.K. Seelam, S. Laassiri, K. Ainassaari, R. Brahmi, R.L. Keiski, Catalysts 5(3), 1092 (2015)

    Article  CAS  Google Scholar 

  7. J.J. Willis, E.D. Goodman, L. Wu, A.R. Riscoe, P. Martins, C.J. Tassone, M. Cargnello, J. Am. Chem. Soc. 139(4), 11989 (2017)

    Article  CAS  PubMed  Google Scholar 

  8. R. Horn, R. Schlögl, Catal. Lett. 145(1), 23 (2015)

    Article  CAS  Google Scholar 

  9. M.C. Alvarez-Galvan, N. Mota, M. Ojeda, S. Rojas, R.N. Navarro, J.L. Fierro, Biofuels 2(3), 325 (2011)

    Article  CAS  Google Scholar 

  10. X. Li, Y. Liu, J. Deng, S. Xie, X. Zhao, Y. Zhang, K. Zhang, H. Arandiyan, G. Guo, H. Dai, Appl. Surf. Sci. 403, 590 (2017)

    Article  CAS  Google Scholar 

  11. Z. Gao, R. Wang, J.A.C.C. Cardiovasc, Interv. 3(10), 1035 (2010)

    Google Scholar 

  12. G. Zhao, X. Pan, Z. Zhang, Y. Liu, Y. Lu, J. Catal. 384, 122 (2020)

    Article  CAS  Google Scholar 

  13. Y. Sim, D. Kwon, S. An, J.M. Ha, T.S. Oh, J.C. Jung, Mol. Catal. 489, 11295 (2020)

    Google Scholar 

  14. V. Bashan, Y. Ust, Int. J. Energy Res. 384, 122 (2019)

    Google Scholar 

  15. L. He, Y. Fan, J. Bellettre, J. Yue, L. Luo, mechanisms. Renew. Sust. Energ. Rev. 119, 109589 (2020)

    Article  CAS  Google Scholar 

  16. L. Oleksenko, G. Fedorenko, N. Maksymovych, Res. Chem. Intermed. 45(8), 4101 (2019)

    Article  CAS  Google Scholar 

  17. R.W. Sidwell, H. Zhu, R.J. Kee, D.T. Wickham, Combust Flame. 134(1–2), 55 (2003)

    Article  CAS  Google Scholar 

  18. Y. Sun, J. Liu, N. Yang, Y. Zhu, Lancet. Infect. Dis. 17(10), 1053 (2017)

    Google Scholar 

  19. M. Wu, W. Li, A.T. Ogunbiyi, G. Guo, F. Xue, K. Chen, B. Zhang, ChemCatChem 13(2), 664 (2021)

    Article  CAS  Google Scholar 

  20. J. Faye, A. Baylet, M. Trentesaux, S. Royer, F. Dumeignil, D. Duprez, S. Valange, J.M. Tatibouët, Appl. Catal. B: Environ. 126, 134 (2012)

    Article  CAS  Google Scholar 

  21. A. Toso, S. Colussi, S. Padigapaty, C. de Leitenburg, A. Trovarelli, Appl. Catal. B: Environ. 230, 237 (2018)

    Article  CAS  Google Scholar 

  22. R. Gholam, M. Alyani, K.J. Smith, Catalysts 5(2), 561 (2015)

    Article  CAS  Google Scholar 

  23. H.U. Ruisheng, B. Yaqin, D.U. Hangyu, H. Zhang, D.U. Yanfei, J. Zhang, Z. Qihua, J. Rare Earths. 33(12), 1284 (2015)

    Article  CAS  Google Scholar 

  24. H. Chen, J. Li, W. Cui, Z. Fei, Q. Tian, Q. Liu, X. Chen, M. Cui, Z. Zhang, J. Tang, X. Qiao, Appl. Surf. Sci. 505, 144112 (2020)

    Article  CAS  Google Scholar 

  25. X.P. Xiang, L.H. Zhao, B.T. Teng, J.J. Lang, X. Hu, T. Li, Y.A. Fang, M.F. Luo, J.J. Lin, Appl. Surf. Sci. 276, 328 (2013)

    Article  CAS  Google Scholar 

  26. F. Polo-Garzon, V. Fung, Z. Wu, D.E. Jiang. (2018)

  27. E.A. Lombardo, M.A. Ulla, Res. Chem. Intermed. 24(5), 581 (1998)

    Article  CAS  Google Scholar 

  28. L. Jurado, P. Vasiliki, S. Thomas, A. Roger, Appl. Catal. B: Environ. 299, 120687 (2021)

    Article  CAS  Google Scholar 

  29. V. Sydorchuk, L. Lutsyuk, V. Shved, V. Hreb, A. Kondyr, O. Zakutevskyy, L. Vasylechko, Res. Chem. Intermed. 46(3), 1909 (2020)

    Article  CAS  Google Scholar 

  30. A. Jahangiri, M. Saidi, F. Salimi, A. Mohammadi, Res. Chem. Intermed. 44, 1755 (2018)

    Article  CAS  Google Scholar 

  31. X. Weng, Q. Meng, J. Liu, W. Jiang, S. Pattisson, Z. Wu, Environ. Technol. 53(2), 884 (2018)

    Article  CAS  Google Scholar 

  32. K. Langfeld, R. Marschner, B. Frank, R. Schomäcker, ChemCatChem 3(8), 1354 (2011)

    Article  CAS  Google Scholar 

  33. Y. Yi, H. Liu, B. Chu, Z. Qin, L. Dong, H. He, C. Tang, M. Fan, L. Bin, Chem. Eng. J. 369, 511 (2019)

    Article  CAS  Google Scholar 

  34. J. Cihlar Jr., R. Vrba, K. Castkova, J. Cihlar, Int. J. Hydrog. Energy. 42(31), 19920 (2017)

    Article  CAS  Google Scholar 

  35. K. Zhao, J. Chen, H. Li, A. Zheng, F. He, J. Energy Inst. 92(3), 594 (2019)

    Article  CAS  Google Scholar 

  36. A. Jangam, S. Das, S. Pati, S. Kawi, Appl. Catal. A Gen. 613, 118013 (2021)

    Article  CAS  Google Scholar 

  37. X. Yang, Q. Gao, Z. Zhao, Y. Guo, L. Wang, Y. Wang, W. Zhan, Appl. Catal. B: Environ. 239, 273 (2018)

    Google Scholar 

  38. J. Yang, Y. Guo, Chin. Chem. Lett. 29(2), 252 (2018)

    Article  CAS  Google Scholar 

  39. P.A. Répécaud, H. Kaper, C.M. Richard, F. Can, N. Bion, ChemCatChem 9(12), 2095 (2017)

    Article  CAS  Google Scholar 

  40. F. Zasada, J. Janas, W. Piskorz, M. Gorczyńska, Z. Sojka, ACS Catal. 7(4), 2853 (2017)

    Article  CAS  Google Scholar 

  41. L. Forni L, I. Rossetti, Appl. Catal. B: Environ. 38(1), 29 (2002)

  42. M.A. Pena, J.L. Fierro, Chem. Rev. 101(7), 1981 (2001)

    Article  CAS  PubMed  Google Scholar 

  43. Y. Zheng, R. Ran, S.Z. Qiao, Z. Shao, Int. J. Hydrog. Energy 37(5), 4328 (2012)

    Article  CAS  Google Scholar 

  44. J.S. Yoon, Y.S. Lim, B.H. Choi, H.J. Hwang, Int. J. Hydrog. Energy 39(15), 7955 (2014)

    Article  CAS  Google Scholar 

  45. H. Najjar, J.F. Lamonier, O. Mentré, J.M. Giraudon, H. Batis, Appl. Catal. A Gen. 469, 98 (2014)

    Article  CAS  Google Scholar 

  46. C. Li, W. Wang, N. Zhao, Y. Liu, B. He, F. Hu, C. Chen, Appl. Catal. B: Environ. 102(1–2), 78 (2011)

    Article  CAS  Google Scholar 

  47. G. Mitran, S. Chen, D.K. Seo, Mol. Catal. 483, 110704 (2020)

    Article  CAS  Google Scholar 

  48. N. Miniajluk, J. Trawczyński, M. Zawadzki, Appl. Catal. A Gen. 531, 119 (2017)

    Article  CAS  Google Scholar 

  49. Y. Farhang, E. Taheri-Nassaj, M. Rezaei, Ceram. Int. 44(17), 21499 (2018)

    Article  CAS  Google Scholar 

  50. R.S. Kalubarme, G.E. Park, K.N. Jung, K.H. Shin, W.H. Ryu, C.J. Park, J. Electrochem. Soc. 161(6), A880 (2014)

    Article  CAS  Google Scholar 

  51. G.R. Moradi, F. Khosravian, M. Rahmanzadeh, (2012) J. CO2. Util. 6 7

  52. M. Abdolrahmani, M. Parvari, M. Habibpoor, Chinese. J. Catal. 31(4), 394 (2010)

    CAS  Google Scholar 

  53. Â.A. Oliveira, R.L. Medeiros, G.P. Figueredo, H.P. Macedo, R.M. Braga, Int. J. Hydrog. Energy. 43(20), 9696 (2018)

    Article  CAS  Google Scholar 

  54. G. Pecchi, R. Morales, E.J. Delgado, R. Jimenez, M. Fraga, J. Chil. Chem. Soc. 59(4), 2725 (2014)

    Article  CAS  Google Scholar 

  55. G. Liu, J. Li, K. Yang, W. Tang, H. Liu, J. Yang, R. Yue, Y. Chen, Particuology. 19, 60 (2015)

    Article  CAS  Google Scholar 

  56. M. Shamsipur, S.M. Pourmortazavi, S.S. Hajimirsadeghi, M.M. Zahedi, M. Rahimi Nasrabadi, Ceram. Int. 39(1), 819 (2013)

    CAS  Google Scholar 

  57. F.A. López, T. Cebriano, I. García-Díaz, P. Fernández, O. Rodríguez, A.L. Fernández, J. Clean. Prod. 148, 795 (2017)

    Article  CAS  Google Scholar 

  58. D.V. Dharmadhikari, S.K. Nikam, A.A. Athawale, J. Alloys Compd. 590, 486 (2014)

    Article  CAS  Google Scholar 

  59. I. Habib, A. Sajawal, G. Murtaza, M. Ishfaq, N. Muhammad, G. Farid, S. Sharif, M.N. Akhtar, S. Salim, Mater. Res. Express. 5(7), 075018 (2018)

    Article  CAS  Google Scholar 

  60. M. Gupta, P. Yadav, W. Khan, A. Azam, A.H. Naqvi, R.K. Kotnala, Adv Mater. Lett 3(3), 220 (2012)

    Article  CAS  Google Scholar 

  61. D. Raoufi, Renew. Energy. 50, 932 (2013)

    Article  CAS  Google Scholar 

  62. K. Kajiyama, Y.I. Izato, A. Miyake, J. Therm. Anal. Calorim. 11(3), 1475 (2013)

    Article  CAS  Google Scholar 

  63. Q. Meng, W. Wang, X. Weng, Y. Liu, H. Wang, W. Zhongbiao, J. Phys. Chem. C. 120(6), 3259–3266 (2016).

    Article  CAS  Google Scholar 

  64. L. Giebeler, D. Kießling, G. Wendt G, Chem. Eng. Technol. 30(7), 889 (2007)

    Article  CAS  Google Scholar 

  65. F. Touahra, A. Rabahi, R. Chebout, A. Boudjemaa, D. Lerari, M. Sehailia, D. Halliche, K. Bachari, Int. J. Hydrog. Energy. 41(4), 2477 (2016)

    Article  CAS  Google Scholar 

  66. Y. Liu, H. Dai, J. Deng, L. Zhang, B. Gao, Y. Wang, X. Li, S. Xie, G. Guo, Appl. Catal. B: Environ. 140, 317 (2013)

    Article  CAS  Google Scholar 

  67. M. Ao, G.H. Pham, V. Sage, V. Pareek, S. Liu, Fuel Process. Technol. 193, 141 (2019)

    Article  CAS  Google Scholar 

  68. Y. Luo, K. Wang, J. Zuo, Q. Qian, Y. Xu, X. Liu, H. Xue, Q. Chen, Catal. Sci. Technol. 7(2), 496 (2017)

    CAS  Google Scholar 

  69. J. Zhu, H. Li, L. Zhong, P. Xiao, X. Xu, X. Yang, Z. Zhao, J. Li, ACS Catal. 4(9), 2917 (2014)

    Article  CAS  Google Scholar 

  70. B. Li, Q. Yang, T. Peng, J. Chen, L. Deng, D. Wang, X. Hong, J. Li, Chem. Eng. J. 366, 92 (2019)

    Article  CAS  Google Scholar 

  71. S. Wang, Q. Liu, Z. Zhao, C. Fan, X. Chen, G. Xu, M. Wu, J. Chen, J. Li, Ind. Eng. Chem. Res. 59(14), 6556 (2020)

    Article  CAS  Google Scholar 

  72. W. Tang, X. Wu, D. Li, Z. Wang, G. Liu, H. Liu, Y. Chen, J. Mater. Chem. A. 2(8), 2544 (2014)

    Article  CAS  Google Scholar 

  73. Y. Du, X. Zhu, H. Wang, Y. Wei, K. Li, J. Energy Inst. 89(4), 745 (2016)

    Article  CAS  Google Scholar 

  74. Y. Zhu, Y. Sun, X. Niu, F. Yuan, H. Fu, Catal. Lett. 135(1), 152 (2010)

    Article  CAS  Google Scholar 

  75. Z.J. Sui, L. Vradman, L. Reizner, M.V. Landau, M. Herskowitz, Catal. Commun. 12(15), 1437 (2011)

    Article  CAS  Google Scholar 

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Iran National Science Foundation.

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  1. Catalyst and Nanomaterials Research Laboratory (CNMRL), School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, 16765-163, Iran

    Maryam Mirasgari, Seyed Mehdi Alavi & Mehran Rezaei

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  1. Maryam Mirasgari
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Mirasgari, M., Alavi, S.M. & Rezaei, M. Effects of partial substitution of Cu by Mn and Co in LaCu0.5Ni0.5O3 catalyst synthesized by mechanochemical method in the total oxidation of methane. Res Chem Intermed 48, 3811–3834 (2022). https://doi.org/10.1007/s11164-022-04775-w

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