Skip to main content
SpringerLink
Log in

Fabrication of La (III) supported on CoFe2O4 MNPs: a novel and efficient heterogeneous catalyst for selective oxidation of sulfides and synthesis of symmetrical disulfides

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

This paper reports the fabrication of La supported on CoFe2O4 nanoparticles through tryptophan (Trp) post-functionalization modification of CoFe2O4 which can be used as an efficient recyclable nanocatalyst. The layer (Trp) on the surface of CoFe2O4 nanoparticles offers large surface area for supporting La (III). The as-prepared CoFe2O4/Trp/La nanocatalyst assemblies exhibit high catalytic activity and chemo-selectivity for the selective oxidation of sulfides and synthesis of symmetrical disulfides. Furthermore, the nanocatalyst displays a good recoverable property during the catalytic procedure by easy and efficient separation from the reaction system and it was reused several periods without any remarkable decrease in the catalytic activity and selectivity.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Scheme 2
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Scheme 3
Scheme 4
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. A. Ghorbani-Choghamarani, B. Ghasemi, Z. Safari, G. Azadi, Catal. Commun. 60, 70 (2015)

    Article  CAS  Google Scholar 

  2. T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Appl. Organomet. Chem. 32, e3974 (2018)

    Article  Google Scholar 

  3. S. Molaei, T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Microporous Mesoporous Mater. 272, 241 (2018)

    Article  CAS  Google Scholar 

  4. N. Moeini, T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Appl. Organomet. Chem. 32, e4445 (2018)

    Article  Google Scholar 

  5. M. Kazemi, L. Shiri, Mini Rev. Org. Chem. 15, 86 (2018)

    Article  CAS  Google Scholar 

  6. S. Molaei, M. Ghadermazi, Appl. Organomet. Chem. 33, e4972 (2019)

    Google Scholar 

  7. S. Molaei, M. Ghadermazi, Appl. Organomet. Chem. 34, e5328 (2020)

    Article  CAS  Google Scholar 

  8. V. Polshettiwar, R. Luque, A. Fihri, H. Zhu, M. Bouhrara, J.-M. Basset, Chem. Rev. 111, 3036 (2011)

    Article  CAS  PubMed  Google Scholar 

  9. S. Molaei, M. Ghadermazi, Solid State Sci. 101, 106148 (2020)

    Article  CAS  Google Scholar 

  10. S. Molaei, T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Catal Lett. 148, 1834 (2018)

    Article  CAS  Google Scholar 

  11. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Appl. Organomet. Chem. 31, e3596 (2017)

    Article  Google Scholar 

  12. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Aust. J. Chem. 69, 585 (2016)

    Article  CAS  Google Scholar 

  13. S. Molaei, M. Ghadermazi, Appl. Organomet. Chem. 33, e4854 (2019)

    Google Scholar 

  14. S. Molaei, M. Ghadermazi, Microporous Mesoporous Mater. 319, 110990 (2021)

    Article  CAS  Google Scholar 

  15. H.-J. Xu, X. Wan, Y. Geng, X.-L. Xu, Curr. Org. Chem. 17, 1034 (2013)

    Article  CAS  Google Scholar 

  16. D. Wang, D. Astruc, Chem. Rev. 114, 6949 (2014)

    Article  CAS  PubMed  Google Scholar 

  17. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Aust. J. Chem. 70, 9 (2017)

    Article  CAS  Google Scholar 

  18. S. Molaei, T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Polyhedron 156, 35 (2018)

    Article  CAS  Google Scholar 

  19. S. Molaei, T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, Appl. Organomet. Chem. 33, e4649 (2019)

    Article  Google Scholar 

  20. T. Cheng, D. Zhang, H. Li, G. Liu, Green Chem. 16, 3401 (2014)

    Article  CAS  Google Scholar 

  21. Y. Zhu, L.P. Stubbs, F. Ho, R. Liu, C.P. Ship, J.A. Maguire, N.S. Hosmane, ChemCatChem 2, 365 (2010)

    Article  CAS  Google Scholar 

  22. D. Zhang, C. Zhou, Z. Sun, L.-Z. Wu, C.-H. Tung, T. Zhang, Nanoscale 4, 6244 (2012)

    Article  CAS  PubMed  Google Scholar 

  23. M.B. Gawande, P.S. Branco, R.S. Varma, Chem. Soc. Rev. 42, 3371 (2013)

    Article  CAS  PubMed  Google Scholar 

  24. K.V.S. Ranganath, F. Glorius, Catal. Sci. Technol. 1, 13 (2011)

    Article  CAS  Google Scholar 

  25. L. Shiri, S. Rahmati, Z. Ramezani Nejad, M. Kazemi, Appl. Organomet. Chem. 31, e3687 (2017)

    Article  Google Scholar 

  26. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Res. Chem. Intermed. 43, 2707 (2017)

    Article  CAS  Google Scholar 

  27. L. Shiri, H. Narimani, M. Kazemi, Appl. Organomet. Chem. 32, e3927 (2018)

    Article  Google Scholar 

  28. L. Shiri, S. Zarei, M. Kazemi, D. Sheikh, Appl. Organomet. Chem. 32, e3938 (2018)

    Article  Google Scholar 

  29. L. Shiri, L. Heidari, M. Kazemi, Appl. Organomet. Chem. 32, e3943 (2018)

    Article  Google Scholar 

  30. L. Shiri, M. Kazemi, Phosphorus Sulfur Silicon Relat. Elem. 192, 1171 (2017)

    Article  CAS  Google Scholar 

  31. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Monatsh. Chem. 148, 1131 (2017)

    Article  CAS  Google Scholar 

  32. V.K. Das, A.J. Thakur, Appl. Catal. A Gen. 470, 97 (2014)

    Article  CAS  Google Scholar 

  33. M. Esmaeilpour, A.R. Sardarian, J. Javidi, Appl. Catal. A Gen. 445, 359 (2012)

    Article  Google Scholar 

  34. R. Ghahremanzadeh, Z. Rashid, A.H. Zarnani, H. Naeimi, Appl. Catal. A Gen. 467, 270 (2013)

    Article  CAS  Google Scholar 

  35. F. Nador, M.A. Volpe, F. Alonso, A. Feldhoff, A. Kirschning, G. Radivoy, Appl. Catal. A Gen. 455, 39 (2013)

    Article  CAS  Google Scholar 

  36. A. Rostami, B. Atashkar, D. Moradi, Appl. Catal. A Gen. 467, 7 (2013)

    Article  CAS  Google Scholar 

  37. S. Sobhani, M. Bazrafshan, A.A. Delluei, Z.P. Parizi, Appl. Catal. A Gen. 454, 145 (2013)

    Article  CAS  Google Scholar 

  38. S. Sobhani, M. Honarmand, Appl. Catal. A Gen. 467, 456 (2013)

    Article  CAS  Google Scholar 

  39. S. Sorkhabi, M. Ghadermazi, R. Mozafari, ChemistrySelect 6, 1555 (2021)

    Article  CAS  Google Scholar 

  40. N. Yarmohammadi, M. Ghadermazi, R. Mozafari, RSC Adv. 11, 9366 (2021)

    Article  CAS  Google Scholar 

  41. N. Moeini, M. Ghadermazi, A. Ghorbani-Choghamarani, Polyhedron 170, 278 (2019)

    Article  CAS  Google Scholar 

  42. B.I. Kharisov, H.V.R. Dias, O.V. Kharissova, Arab. J. Chem. 12, 1234 (2019)

    Article  CAS  Google Scholar 

  43. X. Pang, W. Fu, H. Yang, H. Zhu, J. Xu, X. Li, G. Zou, Mater. Res. Bull. 44, 360 (2009)

    Article  CAS  Google Scholar 

  44. M. Kurian, S. Thankachan, D.S. Nair, E.K. Aswathy, A. Babu, A. Thomas, B.K. Kt, J. Adv. Ceram. 4, 199 (2015)

    Article  CAS  Google Scholar 

  45. E. Swatsitang, S. Phokha, S. Hunpratub, B. Usher, A. Bootchanont, S. Maensiri, P. Chindaprasirt, J. Alloys Compd. 664, 792 (2016)

    Article  CAS  Google Scholar 

  46. M.A.G. Soler, E.C.D. Lima, S.W. da Silva, T.F.O. Melo, A.C.M. Pimenta, J.P. Sinnecker, R.B. Azevedo, V.K. Garg, A.C. Oliveira, M.A. Novak, Langmuir 23, 9611 (2007)

    Article  CAS  PubMed  Google Scholar 

  47. B. Wang, B. Li, B. Zhao, C.Y. Li, J. Am. Chem. Soc. 130, 11594 (2008)

    Article  CAS  PubMed  Google Scholar 

  48. A.R. Bueno, M.L. Gregori, M.C.S. Nobrega, Mater. Chem. Phys. 105, 229 (2007)

    Article  CAS  Google Scholar 

  49. S. Sagadevan, J. Podder, I. Das, Recent Trends Mater. Sci. Appl. 145 (2017)

  50. Z. Ding, W. Wang, Y. Zhang, F. Li, J.P. Liu, J. Alloy Compd. 640, 362 (2015)

    Article  CAS  Google Scholar 

  51. A.T. Raghavender, Sci. Technol. Arts Res. J. 2, 01 (2013)

    Article  CAS  Google Scholar 

  52. Z. Zhou, Y. Zhang, Z. Wang, W. Wei, W. Tang, J. Shi, R. Xiong, Appl. Surf. Sci. 254, 6972 (2008)

    Article  CAS  Google Scholar 

  53. M.B. Gawande, Y. Monga, R. Zboril, R.K. Sharma, Coord. Chem. Rev. 288, 118 (2015)

    Article  CAS  Google Scholar 

  54. M.C. Carreño, Chem. Rev. 95, 1717 (1995)

    Article  Google Scholar 

  55. T. Tamoradi, M. Ghadermazi, A. Ghorbani-Choghamarani, S. Molaei, Res. Chem. Intermed. 44, 4259 (2018)

    Article  CAS  Google Scholar 

  56. J.M. Khurana, A.K. Panda, A. Ray, A. Gogia, Org. Prep. Proced. Int. 28, 234 (1996)

    Article  CAS  Google Scholar 

  57. G.W. Breton, J.D. Fields, P.J. Kropp, Tetrahedron Lett. 36, 3825 (1995)

    Article  Google Scholar 

  58. M. Hirano, H. Kudo, T. Morimoto, Bull. Chem. Soc. Jpn. 67, 1492 (1994)

    Article  CAS  Google Scholar 

  59. A.R. Hajipour, I. Mohammadpoor-Baltork, G. Kianfar, Indian J. Chem. (1999)

  60. H.E. Folsom, J. Castrillón, J. Synth. Commun. 22, 1799 (1992)

    Article  CAS  Google Scholar 

  61. M. Hirano, H. Kudo, T. Morimoto, Bull. Chem. Soc. Jpn. 65, 1744 (1992)

    Article  CAS  Google Scholar 

  62. M. Hirano, S. Yakabe, J.H. Clark, H. Kudo, T. Morimoto, Synth. Commun. 26, 1875 (1996)

    Article  CAS  Google Scholar 

  63. M.H. Ali, W.C. Stevens, Synthesis 1997, 764 (1997)

    Article  Google Scholar 

  64. A. Ogawa, Y. Nishiyama, N. Kambe, S. Murai, N. Sonoda, Tetrahedron Lett. 28, 3271 (1987)

    Article  CAS  Google Scholar 

  65. J.R. Johnson, W.F. Bruce, J.D. Dutcher, J. Am. Chem. Soc. 65, 2005 (1943)

    Article  CAS  Google Scholar 

  66. S. Molaei, M. Ghadermazi, Solid State Sci. 100, 106091 (2020)

    Article  CAS  Google Scholar 

  67. H. Firouzabadi, I. Mohammadpour-Baltork, Bull. Chem. Soc. Jpn. 65, 1131 (1992)

    Article  CAS  Google Scholar 

  68. A. McKillop, D. Koyuncu, A. Krief, W. Dumont, P. Renier, M. Trabelsi, Tetrahedron Lett. 31, 5007 (1990)

    Article  CAS  Google Scholar 

  69. N. Iranpoor, H. Firouzabadi, M.A. Zolfigol, Synth. Commun. 28, 367 (1998)

    Article  CAS  Google Scholar 

  70. L. Shiri, A. Ghorbani-Choghamarani, M. Kazemi, Aust. J. Chem. 70, 9 (2016)

    Article  Google Scholar 

  71. M. Oliverio, M. Nardi, P. Costanzo, L.M. Di Gioia, A. Procopio, Sustainability. 10, 721 (2018)

  72. A. Reghioua, D. Barkat, A.H. Jawad, A.S. Abdulhameed, S. Rangabhashiyam, M.R. Khan, Z.A. Alothman, J. Polym. Environ. 29, 3932–3947 (2021)

  73. Z. Zhang, Y. Jiang, M. Chi, Z. Yang, G. Nie, X. Lu, C. Wang, Appl. Surf. Sci. 363, 578 (2016)

    Article  CAS  Google Scholar 

  74. R. Das, D. Chakraborty, Tetrahedron Lett. 51, 6255 (2010)

    Article  CAS  Google Scholar 

  75. A. Ghorbani-Choghamarani, P. Moradi, B. Tahmasbi, RSC Adv. 6, 56458 (2016)

    Article  CAS  Google Scholar 

  76. A.M.I. Jayaseeli, S. Rajagopal, J. Mol. Catal. Chem. 309, 103 (2009)

    Article  CAS  Google Scholar 

  77. A. Mary Imelda Jayaseeli, A. Ramdass, S. Rajagopal, Polyhedron 100, 59 (2015)

    Article  CAS  Google Scholar 

  78. B. Karimi, M. Ghoreishi-Nezhad, J.H. Clark, Org. Lett. 7, 625 (2005)

    Article  CAS  PubMed  Google Scholar 

  79. M. Nikoorazm, A. Ghorbani-Choghamarani, H. Mahdavi, S.M. Esmaeili, Microporous Mesoporous Mater. 211, 174 (2015)

    Article  CAS  Google Scholar 

  80. A. Dhakshinamoorthy, K. Pitchumani, Catal. Commun. 10, 872 (2009)

    Article  CAS  Google Scholar 

  81. D. Habibi, M.A. Zolfigol, M. Safaiee, A. Shamsian, A. Ghorbani-Choghamarani, Catal. Commun. 10, 1257 (2009)

    Article  CAS  Google Scholar 

  82. T. Tamoradi, A. Ghorbani-Choghamarani, M. Ghadermazi, NJC 41, 11714 (2017)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are deeply grateful to the University of Kurdistan for the financial support and also Erfan Ghadermazi for their help on this research project.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Somayeh Molaei, Mohammad Ghadermazi & Nazanin Moeini

Authors
  1. Somayeh Molaei
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohammad Ghadermazi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nazanin Moeini
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Ghadermazi.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Molaei, S., Ghadermazi, M. & Moeini, N. Fabrication of La (III) supported on CoFe2O4 MNPs: a novel and efficient heterogeneous catalyst for selective oxidation of sulfides and synthesis of symmetrical disulfides. Res Chem Intermed 48, 771–793 (2022). https://doi.org/10.1007/s11164-021-04629-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-021-04629-x

Keywords

Search

Navigation