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A binuclear gadolinium complex of 8-hydroxyquinoline-2-carbaldehyde salicylhydrazone: structural characterisation and photoluminescence properties

Abstract

A dibasic tetradentate N3O3 Schiff base ligand {(Z)-2-hydroxy-N′-((8-hydroxyquinolin-2-yl)methylene)benzohydrazide}(H3L) and its binuclear phenoxido-bridged gadolinium complex, [Gd2(HL)2(NO3)2(DMF)4], were synthesised. The ligand was characterised by 1H-NMR, ESI-Mass, FT-IR, and UV–visible spectroscopic methods. The gadolinium complex was characterised by FT-IR, UV–visible spectroscopy, and single-crystal X-ray diffraction. The central gadolinium(III) ion is nine-coordinated, with a distorted tri-capped-trigonal-prismatic geometry. The equatorial coordination sites are satisfied by donor atoms such as phenolate oxygen in μ2 bridging modes, quinoline nitrogen, azomethine nitrogen from the 8-hydroxyquinoline-2-carbaldehyde and one carbonyl oxygen of salicyl moiety. In addition, two DMF molecules via their carbonyl oxygens and one nitrate in a bidentate fashion via O1 and O2 in the axial region complete the coordination. The gadolinium ions are separated by a distance of 4.04 Å in the complex. The Photoluminescence properties of the ligand and the gadolinium complex were studied in the solid-state at room temperature.

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Acknowledgements

Author Mukesh Kumar thank the Indian Institute of Technology (ISM) Dhanbad for providing financial assistance as a Research Fellowship. The authors are thankful to Dr S. K Sharma and Navneet Kumar, Department of Physics, Indian Institute of Technology (ISM) Dhanbad, for providing the photoluminescence analysis facility. The authors are also grateful to the Sophisticated Analytical Instrument Facility, Punjab University Chandigarh, for providing the NMR and mass spectral facilities.

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Kumar, M., Kumar, A., Manav, N. et al. A binuclear gadolinium complex of 8-hydroxyquinoline-2-carbaldehyde salicylhydrazone: structural characterisation and photoluminescence properties. Res Chem Intermed (2021). https://doi.org/10.1007/s11164-021-04589-2

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Keywords

  • Gadolinium complex
  • Hydroxyquinoline
  • Crystal structure
  • Photoluminescence
  • CIE diagram