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Keggin-type heteropoly-11-molybdo-1-vanadophosphoric acid supported montmorillonite K-10 clay-catalysed one-pot multi-component synthesis of chromeno[2,3-b]indoles

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Abstract

One-pot three-component synthesis of twelve different chromeno[2,3-b]indole derivatives were achieved by the condensation of β-naphthol, oxindole and various substituted aldehydes. Two more chromeno[2,3-b]indole derivatives were also synthesized through one-pot two-component condensation of salicylaldehyde with oxindole/chlorooxindole. Both the condensations were achieved by using Keggin-type heteropoly-11-molybdo-1-vanadophosphoric acid, H4[PVMo11O40] supported on montmorillonite K-10 clay for about 10% as catalyst under environmentally benign solvent-free reaction condition. Shorter reaction time, excellent yield of product, sustainability of catalytic material and simple workup procedure under green experimental conditions are the advantages of this protocol.

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Acknowledgements

The authors thank the Managing Board authorities of Virudhunagar Hindu Nadars’ Senthikumara Nadar College (Autonomous), Virudhunagar 626001, Tamil Nadu, India, for providing infra-structural and research facilities.

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Authors and Affiliations

  1. Department of Chemistry, V.H.N. Senthikumara Nadar College (Autonomous), Virudhunagar, 626001, India

    Prasanna Antony Muthu & Sami Ponnusamy

  2. Department of Chemistry, V.V.Vanniaperumal College for Women, Virudhunagar, 626001, India

    Prasanna Antony Muthu

  3. Nanomaterials Laboratory, Department of Chemistry, International Research Centre, Kalasalingam Academy of Research and Education (Deemed To Be University), Krishnankoil, 626126, India

    Kumaresan Murugan & Swaminathan Meenakshisundaram

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  1. Prasanna Antony Muthu
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  2. Kumaresan Murugan
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  3. Swaminathan Meenakshisundaram
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  4. Sami Ponnusamy
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Correspondence to Sami Ponnusamy.

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Antony Muthu, P., Murugan, K., Meenakshisundaram, S. et al. Keggin-type heteropoly-11-molybdo-1-vanadophosphoric acid supported montmorillonite K-10 clay-catalysed one-pot multi-component synthesis of chromeno[2,3-b]indoles. Res Chem Intermed 47, 3583–3595 (2021). https://doi.org/10.1007/s11164-021-04483-x

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