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Pueraria lobata leaf extract as green corrosion inhibitor for low carbon steel in 1.0 M HCl solution

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Abstract

Plant corrosion inhibitors in acid-pickling environment have the advantages of wide source, low cost and environmental protection. Pueraria lobata leaf extract (PLLE) was prepared by the combination of soaking method and ultrasonic extraction method. HPLC characterization found that PLLE contains some active ingredients, such as Puerarin, Biochanin, Daidzin and Daidzein. The corrosion inhibition of PLLE on 10# steel in 1.0 M HCl solution was studied by weight loss analysis, potentiodynamic polarization measurement, electrochemical impedance spectroscopy, scanning Kelvin probe test (SKP) and scanning electron microscopy. The results show that PLLE can effectively inhibit the corrosion of 10# steel in HCl, when the temperature is 25 °C, adding 0.5 g/L PLLE to 1.0 M HCl solution, the corrosion inhibition efficiency of 10# steel can reach up to 94.37%. The SKP results show that after adding PLLE to HCl, the surface potential difference and electrochemical non-uniformity of 10# steel are reduced, and the local corrosion tendency is significantly reduced. Polarization curves and electrochemical impedance spectroscopy indicate that PLLE is a mixed corrosion inhibitor. The adsorption process is mainly chemisorption and obeyed the Langmuir model.

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References

  1. A. Ehsani, M.G. Mahjani, M. Hosseini, R. Safari, R. Moshrefi, H. Mohammad Shiri, J. Coll. Interface. Sci. 490, 444 (2017)

    Article  CAS  Google Scholar 

  2. I. Nadi, Z. Belattmani, B. Sabou, A. Rean, A. Sahibed-Dine, C. Jama, F. Bentiss, Int. J. Biol. Macromol. 28(6), 577 (2019)

  3. Y.L. Rui, J.M. Yu, M.X. Lu, Y.H. Liang, H.J. Tian, Corros. Prot. 28(3), 109 (2008)

    Google Scholar 

  4. S.N. Mehdi, M.S. Ghandchi, Metall. Mater. Trans. A. 46(11), 5139 (2015)

    Article  Google Scholar 

  5. X.H. Liu, J. Du, Q.H. Wang, C.Y. Sun, Surf. Technol. 39(6), 51 (2010)

    Google Scholar 

  6. X. Wang, H. Jiang, L. Hou, W.J. Zhou, H. Wang, S.F. Ren, Surf. Technol. 47(6), 24 (2018)

    Google Scholar 

  7. M.B. Petrovic Mihajlovic, M.B. Radovanovic, Z.Z. Tasic, M.M. Antoijevic, J. Mol. Liq. 225, 127 (2017)

    Article  CAS  Google Scholar 

  8. T.L. Zhang, S.R. Cao, S.S. Dai, W.J. Jiang, H.P. Quan, Corros. Sci. Prot. Technol. 26(4), 329 (2014)

    CAS  Google Scholar 

  9. R. Yıldız, Corros. Sci. 90, 544 (2015)

    Article  Google Scholar 

  10. A.K. Satapathy, G. Gunasekaran, S.C. Sahoo, K. Amit, P.V. Rodrigues, Corros. Sci. 51(12), 2848 (2009)

    Article  CAS  Google Scholar 

  11. A. Singh, M.A. Quraishi, Res. Chem. Intermed. 41(5), 2901 (2015)

    Article  CAS  Google Scholar 

  12. J. Bhawsar, P.K. Jain, P. Jain, Alex. Eng. J. 54(3), 769 (2015)

    Article  Google Scholar 

  13. S. Perumal, S. Muthumanickam, A. Elangovan, R. Karthik, R. Sayee Kannan, K.K. Mothilal, J. Bio Tribo Corros. 3(2), 13 (2017)

    Article  Google Scholar 

  14. A. Singh, Y.H. Lin, E. Ebenso, W.Y. Liu, J. Pan, B. Huang, J. Ind. Eng. Chem. 24, 219 (2015)

    Article  CAS  Google Scholar 

  15. X.J. Li, H. Li, X.G. Huang, Food Sci. Technol. 11, 102 (2006)

    Google Scholar 

  16. X.Y. Wu, L.L. Yang, L.Q. Yang, Y.M. Zou, J.M. Lu, Food Sci. 30(14), 248 (2009)

    CAS  Google Scholar 

  17. Q.L. Wu, Y.Q. Xu, Q.L. Zhang, M.J. Ye, H.H. Wang, Technol. Innovat. Appl. 11, 62 (2016)

    Google Scholar 

  18. X. Zhang, J.X. Wen, Y.X. Liu, X.M. Yang, Surf. Technol. 47(3), 231 (2018)

    Google Scholar 

  19. G. Gece, Corros. Sci. 53(12), 3873 (2011)

    Article  CAS  Google Scholar 

  20. X. Wang, S.F. Ren, D.X. Zhang, H. Jiang, Y. Gu, Int. J. Electrochem. Sci. 13(10), 9888 (2018)

    Article  CAS  Google Scholar 

  21. X. Wang, H. Jiang, D.X. Zhang, L. Hou, W.J. Zhou, Int. J. Electrochem. Sci. 14(2), 1178 (2019)

    Article  CAS  Google Scholar 

  22. M. Talha, Y.C. Ma, Y.H. Lin, A. Singh, W.Y. Liu, X.W. Kong, New J. Chem. 43(4), 1943 (2019)

    Article  CAS  Google Scholar 

  23. M. Pitchaipillai, K. Raj, J. Balasubramanian, Int. J. Miner., Metall. Mater. 21(11), 1083 (2014)

    Article  Google Scholar 

  24. P. Muthukrishnan, P. Prakash, B. Jeyaprabha, K. Shankar, Arab. J. Chem. 12(8), 3345 (2019)

    Article  CAS  Google Scholar 

  25. S.A. Umoren, U.M. Eduok, M.M. Solomon, A.P. Udoh, Arab. J. Chem. 9, 5 (2016)

    Article  Google Scholar 

  26. K.H. Hassan, A.A. Khadom, N.H. Kurshed, S. Afr, J. Chem. Eng. 22, 1 (2016)

    Google Scholar 

  27. A. Ostovari, S.M. Hoseinieh, M. Peikari, S.R. Shadizadeh, S.J. Hashemi, Corros. Sci. 51(9), 1935 (2009)

    Article  CAS  Google Scholar 

  28. A. Singh, K.R. Ansari, X.H. Xu, Z.P. Sun, A. Kumar, Y.H. Lin, Sci. Rep. 791, 14904 (2017)

    Article  Google Scholar 

  29. M. Gobara, A. Baraka, B. Zaghloul, Res. Chem. Intermed. 41(12), 9885 (2015)

    Article  CAS  Google Scholar 

  30. L.L. Liao, S. Mo, H.Q. Luo, J. Coll. Interface Sci. 499, 110 (2017)

    Article  CAS  Google Scholar 

  31. A.S. Fouda, G.Y. El-Awady, W.T. El Behairy, J. Bio Tribo Corros. 4(1), 8 (2018)

    Article  Google Scholar 

  32. Y.W. Tian, Z.P. Lv, X.K. Ru, J.J. Chen, Q. Xiao, Corros. Prot. 37(6), 439 (2016)

    Google Scholar 

  33. K.F. Khaled, M.M. Al-Qahtani, Mater. Chem. Phys. 113(1), 150 (2009)

    Article  CAS  Google Scholar 

  34. S.P. Palanisamy, G. Maheswaran, C. Kamal, G. Venkatesh, Res. Chem. Intermed. 42(12), 7823 (2016)

    Article  CAS  Google Scholar 

  35. C. Loganayagi, C. Kamal, M.G. Sethuraman, Chem. Eng. 2(4), 606 (2014)

    CAS  Google Scholar 

  36. Z.H. Jin, H.H. Ge, W.W. Lin, Y.W. Zong, S.J. Liu, J.M. Shi, Appl. Surf. Sci. 322, 47 (2014)

    Article  CAS  Google Scholar 

  37. N.N. Aung, Y.J. Tan, T. Liu, Corros. Sci. 48(1), 23 (2006)

    Article  Google Scholar 

  38. V. Barranco, E. Onofre, M.L. Escudero, M.C. Garci’a-Alonso, Surf. Coat. Technol. 204(23), 3783 (2010)

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was supported by the National Natural Science Foundation of China (No.51774242)

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Authors and Affiliations

  1. Material Science and Engineering School, Southwest Petroleum University, Chengdu, 610500, People’s Republic of China

    Xia Wang, Qiao Zhang, Huan Jiang, Yue Gu, Xiong Li & Ling-long Xu

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  1. Xia Wang
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  3. Huan Jiang
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Correspondence to Xia Wang.

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Wang, X., Zhang, Q., Jiang, H. et al. Pueraria lobata leaf extract as green corrosion inhibitor for low carbon steel in 1.0 M HCl solution. Res Chem Intermed 47, 1051–1069 (2021). https://doi.org/10.1007/s11164-020-04316-3

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