Skip to main content

Advertisement

SpringerLink
Log in

Methane conversion to higher value-added product and energy co-generation using anodes OF PdCu/C in a solid electrolyte reactor: alkaline fuel cell type monitored by differential mass spectroscopy

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

PdxCuy/C catalysts combinations were employed to CH4 partial oxidation in mild condition using a solid electrolyte reactor—alkaline fuel cell type. The differential mass spectroscopy on line method was used to monitor the oxidation products obtained as methanol, dimethyl ether, methyl formate and potassium formate. It was observed that as the electrical potential of the reactor increases, the generation of products decreases. The best results for conversion of methane into methanol and energy co-generation was obtained from Pd90Cu10/C and Pd50Cu50/C due to better H2O activation effects and adsorption site for CH4 oxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. M. Subrahmanyam, S. Kaneco, N. Alonso-Vante, Appl. Catal. B 23, 169 (1999)

    Article  CAS  Google Scholar 

  2. M.C.L. Santos, L.C. Nunes, L.M.G. Silva, A.S. Ramos, F.C. Fonseca, R.F.B. de Souza, A.O. Neto, ChemistrySelect 4, 11430 (2019)

    Article  CAS  Google Scholar 

  3. J. Jang, K. Shen, C.G. Morales-Guio, Joule 3, 2589 (2019)

    Article  Google Scholar 

  4. V.L. Sushkevich, J.A. van Bokhoven, Catal. Sci. Technol. 10, 382 (2020)

    Article  CAS  Google Scholar 

  5. J. Yang, J. Hao, J. Wei, J. Dai, Y. Li, Fuel 266, 117104 (2020)

    Article  CAS  Google Scholar 

  6. A. Tomita, J. Nakajima, T. Hibino, Angew. Chem. Int. Ed. 47, 1462 (2008)

    Article  CAS  Google Scholar 

  7. R.S. Rocha, L.M. Camargo, M.R.V. Lanza, R. Bertazzoli, Electrocatalysis 1, 224 (2010)

    Article  CAS  Google Scholar 

  8. J. Nandenha, R.M. Piasentin, L.M.G. Silva, E.H. Fontes, A.O. Neto, R.F.B. de Souza, Ionics 25, 5077 (2019)

    Article  CAS  Google Scholar 

  9. Y. Gambo, A.A. Jalil, S. Triwahyono, A.A. Abdulrasheed, J. Ind. Eng. Chem. 59, 218 (2018)

    Article  CAS  Google Scholar 

  10. S. Lim, J.-W. Choi, D.J. Suh, K.H. Song, H.C. Ham, J.-M. Ha, J. Catal. 375, 478 (2019)

    Article  CAS  Google Scholar 

  11. O.B. Ayodele, Energy Convers. Manag. 126, 537 (2016)

    Article  CAS  Google Scholar 

  12. L. Arnarson, P.S. Schmidt, M. Pandey, A. Bagger, K.S. Thygesen, I.E.L. Stephens, J. Rossmeisl, Phys. Chem. Chem. Phys. 20, 11152 (2018)

    Article  CAS  PubMed  Google Scholar 

  13. A. Hameed, I.M.I. Ismail, M. Aslam, M.A. Gondal, Appl. Catal. A 470, 327 (2014)

    Article  CAS  Google Scholar 

  14. X. Yu, V. De Waele, A. Löfberg, V. Ordomsky, A.Y. Khodakov, Nat. Commun. 10, 700 (2019)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  15. M.J. Boyd, A.A. Latimer, C.F. Dickens, A.C. Nielander, C. Hahn, J.K. Nørskov, D.C. Higgins, T.F. Jaramillo, ACS Catal. 9, 7578 (2019)

    Article  CAS  Google Scholar 

  16. B. Lee, T. Hibino, J. Catal. 279, 233 (2011)

    Article  CAS  Google Scholar 

  17. M. Ma, B.J. Jin, P. Li, M.S. Jung, J.I. Kim, Y. Cho, S. Kim, J.H. Moon, J.H. Park, Adv. Sci. 4, 1700379 (2017)

    Article  CAS  Google Scholar 

  18. A. Serov, I.V. Zenyuk, C.G. Arges, M. Chatenet, J. Power Sources 375, 149 (2018)

    Article  CAS  Google Scholar 

  19. H. Meng, D. Zeng, F. Xie, Catalysts 5, 1221 (2015)

    Article  CAS  Google Scholar 

  20. Z. Liu, E. Huang, I. Orozco, W. Liao, R.M. Palomino, N. Rui, T. Duchoň, S. Nemšák, D.C. Grinter, M. Mahapatra, P. Liu, J.A. Rodriguez, S.D. Senanayake, Science 368, 513 (2020)

    Article  CAS  PubMed  Google Scholar 

  21. C. Wang, Y. Cao, H. Wang, Chemosphere 230, 278 (2019)

    Article  CAS  PubMed  Google Scholar 

  22. L. Qin, M. Guo, Y. Liu, Z. Cheng, J.A. Fan, L.-S. Fan, Appl. Catal. B 235, 143 (2018)

    Article  CAS  Google Scholar 

  23. M. Álvarez, P. Marín, S. Ordóñez, Mol. Catal. 487, 110886 (2020)

    Article  CAS  Google Scholar 

  24. S.R. Chowdhury, P. Mukherjee, S.K. Bhattachrya, Int. J. Hydrog. Energy 41, 17072 (2016)

    Article  CAS  Google Scholar 

  25. H. Xiao, W.A. Goddard, T. Cheng, Y. Liu, Proc. Natl. Acad. Sci. 114, 6685 (2017)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  26. G.M. Tomboc, S. Choi, T. Kwon, Y.J. Hwang, K. Lee, Adv. Mater. 32, 1908398 (2020)

    Article  CAS  Google Scholar 

  27. I.H. Boyaci, H.E. Genis, B. Guven, U. Tamer, N. Alper, J. Raman Spectrosc. 43, 1171 (2012)

    Article  CAS  Google Scholar 

  28. R.S. Hyam, J. Lee, E. Cho, J. Khim, H. Lee, J. Nanosci. Nanotechnol. 12, 8396 (2012)

    Article  CAS  PubMed  Google Scholar 

  29. A. Serov, U. Martinez, A. Falase, P. Atanassov, Electrochem. Commun. 22, 193 (2012)

    Article  CAS  Google Scholar 

  30. L. Yang, D. Yan, C. Liu, H. Song, Y. Tang, S. Luo, M. Liu, J. Power Sources 278, 725 (2015)

    Article  CAS  Google Scholar 

  31. C. Ji, S.-N. Yin, S. Sun, S. Yang, Appl. Surf. Sci. 434, 1224 (2018)

    Article  CAS  Google Scholar 

  32. D. Duan, H. Liu, Q. Wang, Y. Wang, S. Liu, Electrochim. Acta 198, 212 (2016)

    Article  CAS  Google Scholar 

  33. Y.-H. Wang, J.-B. He, Electrochim. Acta 66, 45 (2012)

    Article  CAS  Google Scholar 

  34. S.T. Mayer, J. Electrochem. Soc. 139, 426 (1992)

    Article  CAS  Google Scholar 

  35. G. Nogami, Y. Nishiyama, H. Nakamura, J. Electrochem. Soc. 135, 877 (1988)

    Article  CAS  Google Scholar 

  36. L.M.S. Garcia, S. Rajak, K. Chair, C.M. Godoy, A.J. Silva, P.V.R. Gomes, E.A. Sanches, A.S. Ramos, R.F.B. De Souza, A. Duong, A.O. Neto, ACS Omega 5, 16003 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  37. R. Zhou, Y. Zheng, M. Jaroniec, S.-Z. Qiao, ACS Catal. 6, 4720 (2016)

    Article  CAS  Google Scholar 

  38. B. Lee, Y. Sakamoto, D. Hirabayashi, K. Suzuki, T. Hibino, J. Catal. 271, 195 (2010)

    Article  CAS  Google Scholar 

  39. J. Nandenha, I. Nagahama, J. Yamashita, E. Fontes, J. Ayoub, R. de Souza, F. Fonseca, A. Neto, Int. J. Electrochem. Sci 14, 10819 (2019)

    Article  CAS  Google Scholar 

  40. J. Nandenha, E.H. Fontes, R.M. Piasentin, F.C. Fonseca, A.O. Neto, J. Fuel Chem. Technol. 46, 1137 (2018)

    Article  CAS  Google Scholar 

  41. Y. Kanazawa, K. Nukada, Bull. Chem. Soc. Jpn. 35, 612 (1962)

    Article  CAS  Google Scholar 

  42. P.A. Christensen, D. Linares-Moya, J. Phys. Chem. C 114, 1094 (2010)

    Article  CAS  Google Scholar 

  43. V.F. de Carmargo, E.H. Fontes, J. Nandenha, R.F.B. de Souza, A.O. Neto, Res. Chem. Intermed. 46, 1555 (2020)

    Article  CAS  Google Scholar 

  44. F. de MouraSouza, R.F.B. de Souza, B.L. Batista, M.C. dos Santos, F.C. Fonseca, A.O. Neto, J. Nandenha, Res. Chem. Intermed. 46, 2481 (2020)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We are grateful to CAPES, CNPq 300816/2016-2), FAPESP (2014/09087-4, 2014/50279-4 and 2017/11937-4) and CINE-SHELL (ANP)/FAPESP Grants 2017/11937-4 for financial supports.

Author information

Authors and Affiliations

  1. Instituto de Pesquisas Energéticas E Nucleares, IPEN/CNEN-SP, Av. Prof. Lineu Prestes, 2242 Cidade Universitária, São Paulo, SP, CEP 05508-000, Brazil

    C. M. Godoi, M. C. L. Santos, A. J. Silva, T. L. Tagomori, A. S. Ramos, R. F. B. de Souza & A. Oliveira Neto

  2. Faculdades Oswaldo Cruz, R. Brg. Galvão, 540 - Metrô Marechal Deodoro, São Paulo, SP, 01151-000, Brazil

    T. L. Tagomori

Authors
  1. C. M. Godoi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. C. L. Santos
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. J. Silva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. L. Tagomori
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. S. Ramos
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. F. B. de Souza
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. Oliveira Neto
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Oliveira Neto.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Godoi, C.M., Santos, M.C.L., Silva, A.J. et al. Methane conversion to higher value-added product and energy co-generation using anodes OF PdCu/C in a solid electrolyte reactor: alkaline fuel cell type monitored by differential mass spectroscopy. Res Chem Intermed 47, 743–757 (2021). https://doi.org/10.1007/s11164-020-04296-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-020-04296-4

Keywords

Search

Navigation