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Preparation of polyacrylonitrile-based activated carbon fiber for CS2 adsorption

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Abstract

Polyacrylonitrile (PAN)-based activated carbon fiber (ACF) was prepared by CO2 and KOH activation method, respectively, and used for the adsorption of CS2 at room temperature. The adsorbents were characterized by scanning electron microscope, CO2-temperature-programmed desorption and Fourier transform infrared spectroscopy. The adsorption activity of ACF prepared by different conditions (preoxidation process, carbonization temperature, CO2 activation temperature and time, carbon/KOH ratio, KOH activation temperature and time) was studied. The best breakthrough adsorption capacity of CS2 was 55.63 mgS/g when the ACF was activated by CO2 [ACF(I700)-CO2(900 + 90)]. The best breakthrough adsorption capacity of CS2 was 49.52 mgS/g when the activator was KOH [ACF(I700)-KOH(1:1 + 900 + 60)].

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Acknowledgements

This work was supported by National Natural Science Foundation of China [51968034, 21667015, 41807373 and 51708266], National Key R&D Program of China [2018YFC0213400] and the Analysis and Testing Foundation of Kunming University of Science and Technology.

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Authors and Affiliations

  1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Kunlin Li, Kai Li, Ping Ning, Xin Sun, Xin Song & Yingwu Wang

  2. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Chi Wang

  3. National-Regional Engineering Center for Recovery of Waste Gases From Metallurgical and Chemical Industries, Kunming, 650500, People’s Republic of China

    Ping Ning

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  1. Kunlin Li
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  2. Kai Li
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Li, K., Li, K., Wang, C. et al. Preparation of polyacrylonitrile-based activated carbon fiber for CS2 adsorption. Res Chem Intermed 46, 3459–3476 (2020). https://doi.org/10.1007/s11164-020-04156-1

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