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A newly synthesized organic–inorganic hybrid in nano-size including [BW12O40]5− anions and hydrolyzed 2-cyanoguanidine cations as a double working green catalyst

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Abstract

A newly prepared nano-organic–inorganic hybrid compound, videlicet [HPDCD]5[BW12O40]·3H2O (HPDCD = hydrolyzed and protonated 2-cyanoguanidine) (1), has been prepared under reflux condition and analyzed by FT-IR and 1H NMR spectroscopies, TG–DT analysis, FE-SEM, cyclic voltammetry, elemental analyses and also single-crystal and powder X-ray diffraction. Hydrogen bonding is the crucial agent in 1 hybrid structure as can be seen from the X-ray data. In this compound, 3D cage-like cavities are constructed by HPDCD counter-ions through hydrogen bonding. Four types of hydrogen bonds in compound 1 lead to the formation of cage-like cavities. [BW12O40]5− clusters are located into compound 1 cage-like cavities. Five types of HPDCD units create cage-like cavities according to which two types of BW12 clusters are placed between the cavities. Moreover, according to powder X-ray diffraction and field emission SEM analyses, the nano-size of 1 cluster has been confirmed. Furthermore, compound 1 has been considered in terms of the electrocatalytic activity and photocatalytic property.

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Acknowledgements

The authors thank the Research Council of Hakim Sabzevari University and Tsinghua University for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Ali Jamshidi & Farrokhzad Mohammadi Zonoz

  2. Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Ali Jamshidi

  3. Department of Chemistry, Tsinghua University, Beijing, 100084, China

    Yongge Wei

  4. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran

    Ali Samie

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  1. Ali Jamshidi
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Jamshidi, A., Zonoz, F.M., Wei, Y. et al. A newly synthesized organic–inorganic hybrid in nano-size including [BW12O40]5− anions and hydrolyzed 2-cyanoguanidine cations as a double working green catalyst. Res Chem Intermed 46, 3431–3447 (2020). https://doi.org/10.1007/s11164-020-04154-3

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