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High promoting of selective oxidation of ethylbenzene by Mn-ZSM-5 synthesized without organic template and calcination

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Abstract

Acetophenone is a valuable and widely applied intermediate in chemical industry, but limited by the synthesis with low-cost and efficient heterogeneous catalyst. Herein, we report tetrahedral coordination manganese-incorporated ZSM-5 zeolite (Mn-ZSM-5) by three steps involving acid hydrolysis of Mn(NO3)2 with tetraethylorthosilicate, basic aging and hydrothermal crystallization without organic template and calcination. Mn-ZSM-5 was identified by characterizations such as X-ray diffraction, Fourier transform infrared spectra (FTIR), field emission scanning electron microscopy, inductively coupling plasma spectrometer, N2-adsorption/desorption and FTIR, X-ray photoelectron spectroscopy (XPS), electron spin-resonance spectroscopy (ESR), NH3-TPD and H2-TPR. Moreover, tetrahedral coordination Mn atoms successfully incorporate into the framework of ZSM-5 demonstrated by ESR and XPS spectra. Furthermore, Mn-ZSM-5 with high crystallinity performs high and stable catalytic activity in the oxidation of ethylbenzene owing to tetrahedral Mn3+ in the framework of ZSM-5 as catalytic active sites.

Graphic abstract

Tetrahedral coordination manganese-incorporated ZSM-5 zeolites synthesized without organic template and calcination performed high and stable catalytic activity on the oxidation of ethylbenzene owing to tetrahedral Mn3+ as catalytic active sites.

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Acknowledgment

This work was supported by the Natural Science Foundation of China (21776129, 21476108, 21276125, 21908085 and 21573103) and Natural Science Foundation of Jiangsu Province (Nos. BK20170995 and BK20190961).

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Authors and Affiliations

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China

    Xianfeng Liu, Shuying Gao, Fu Yang, Shijian Zhou & Yan Kong

  2. College of Environment Engineering, Nanjing Institute of Technology, Nanjing, 211167, China

    Xianfeng Liu

  3. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu, China

    Fu Yang

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  1. Xianfeng Liu
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Correspondence to Yan Kong.

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Liu, X., Gao, S., Yang, F. et al. High promoting of selective oxidation of ethylbenzene by Mn-ZSM-5 synthesized without organic template and calcination. Res Chem Intermed 46, 2817–2832 (2020). https://doi.org/10.1007/s11164-020-04123-w

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