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Synthesis of new polyaryl-substituted imidazoles bridged on enamine or urea moieties and evaluation of their optical and electrochemical properties

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Abstract

The reaction of the free amine group in polyaryl-substituted imidazole structures with phenyl isocyanate or dimethyl acetylenedicarboxylate gave two new series of polyaryl-substituted imidazoles: biaryl ureas or vinyl esters, respectively. Besides their spectroscopic analysis, we explored the optical and electrochemical properties of these highly conjugated scaffolds. Comparing these properties in two categories of products yielded interesting results.

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Acknowledgements

Authors thank the research affairs of the University of Tabriz for their financial support.

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Authors and Affiliations

  1. Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166614766, Iran

    Ameneh Abolghassemi Fakhree, Roghayeh Mohammadzadeh & Zarrin Ghasemi

  2. Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166614766, Iran

    Esmaeel Alipour

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  1. Ameneh Abolghassemi Fakhree
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  2. Roghayeh Mohammadzadeh
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  3. Esmaeel Alipour
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  4. Zarrin Ghasemi
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Fakhree, A.A., Mohammadzadeh, R., Alipour, E. et al. Synthesis of new polyaryl-substituted imidazoles bridged on enamine or urea moieties and evaluation of their optical and electrochemical properties. Res Chem Intermed 46, 2069–2082 (2020). https://doi.org/10.1007/s11164-020-04078-y

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