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Synthesis and properties of seminaphthorhodafluor red laser dyes

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Abstract

In the present work, we synthesized two seminaphthorhodafluor red laser dyes SNARF-X1 and SNARF-X2 and investigated their photo-physical properties in different solvents and the laser properties in ethanol. It was found that the wavelengths of absorption and fluorescence emission spectra are not very sensitive to the solvent polarity, while the fluorescence intensities decrease with the increase in solvent polarity. SNARF-X1 and SNARF-X2 not only emit tunable red laser (590–670 nm for SNARF-X1 and 600–680 nm for SNARF-X2) but also show high laser conversion efficiency. The above two dyes also show high photo-stability under 532 nm ND:YAG laser irradiation. In this regard, the half-lives of laser efficiency for SNARF-X1 and SNARF-X2 are 7 h and 6 h, respectively.

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Acknowledgements

This work has been supported by the Research Fund of Science and Technology on Particle Transport and Separation Laboratory, the Shanghai Municipal Science and Technology Major Project (2018SHZDZX03), and the Programme of Introducing Talents of Discipline to Universities (B16017).

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Authors and Affiliations

  1. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

    Wei Ming, Xiaojie Hu, Baozhu Tian & Jinlong Zhang

  2. Research Institute of Physical and Chemical Engineering of Nuclear Industry, 168 JinTang Road, Tianjin, 300180, People’s Republic of China

    Zhizhong Zhang, Shunzhou Chang & Risheng Chen

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  1. Wei Ming
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  2. Xiaojie Hu
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  3. Zhizhong Zhang
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  4. Shunzhou Chang
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  5. Risheng Chen
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  6. Baozhu Tian
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  7. Jinlong Zhang
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Correspondence to Baozhu Tian or Jinlong Zhang.

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Ming, W., Hu, X., Zhang, Z. et al. Synthesis and properties of seminaphthorhodafluor red laser dyes. Res Chem Intermed 46, 1991–2002 (2020). https://doi.org/10.1007/s11164-019-04076-9

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