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Polystyrene@graphene oxide-Fe3O4 as a novel and magnetically recyclable nanocatalyst for the efficient multi-component synthesis of spiro indene derivatives

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Abstract

Polystyrene (PS)-coated magnetic graphene oxide (GO-Fe3O4) nanocomposite has been prepared and characterized by FT-IR, TEM and VSM techniques, and its catalytic activity has been evaluated in the multi-component synthesis of two series of indene derivatives. The three-component condensation of ninhydrin/isatin, malononitrile and active methylene-containing compounds and also the four-component condensation of ninhydrin, o-phenylenediamines, malononitrile and active methylene-containing compounds were satisfactorily performed in the presence of PS@GO-Fe3O4 magnetic nanocomposite, and corresponding 2′-aminospiro[indene-2,4′-pyran]-3′-carbonitriles, 2′-aminospiro[indoline-3, 4′-pyran]-3′-carbonitriles and 2′-aminospiro[indeno[1,2-b]quinoxaline-11,4′-pyrane]-3′-carbonitriles were obtained in good-to-excellent yields, respectively. Very shorter reaction times than the reported methods, easy workup procedure and easy separation and reusability of the catalyst are noteworthy advantages of the current method.

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Acknowledgements

The authors thank Hakim Sabzevari University for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Seyedeh Fatemeh Hojati, Amirhassan Amiri & Maryam Mahamed

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  1. Seyedeh Fatemeh Hojati
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  2. Amirhassan Amiri
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Correspondence to Seyedeh Fatemeh Hojati.

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Hojati, S.F., Amiri, A. & Mahamed, M. Polystyrene@graphene oxide-Fe3O4 as a novel and magnetically recyclable nanocatalyst for the efficient multi-component synthesis of spiro indene derivatives. Res Chem Intermed 46, 1091–1107 (2020). https://doi.org/10.1007/s11164-019-04021-w

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