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Ultrasonic synthesis, crystal structure, luminescent, and magnetic properties of a new metal–organic complex based on Ce(IV)–Sr(II)

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Abstract

This paper presents the sonochemical synthesis of a new hetero-metallic inorganic complex, formulated as [(Sr(OH2)5Ce(dipic)3Sr(OH2)6][Ce(dipic)3]·6H2O (1), (dipic = pyridine-2,6-dicarboxylate). The structure of 1 was characterized by elemental analysis, atomic absorption spectroscopy, Fourier transform infrared spectroscopy, and single crystal X-ray diffraction. The complex crystallizes in a triclinic system, space group P-1, with unit cell parameters a = 13.8789 (3) Å, b = 14.1002 (3) Å, and c = 17.0514 (4) Å. It is composed of anionic and cationic parts, and six free water molecules. Inter-molecular hydrogen bonds connect these units to each other and play an important role in the stability of the structure. According to magnetic measurement, complex 1 is a weak ferromagnet at room temperature. The thermal decomposition studied by simultaneous thermogravimetric analysis/differential thermal analysis shows three decomposition stages with the metal oxide as the final residuum. The complex exhibits luminescence.

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Acknowledgements

We are grateful to the University of Zabol for financial support. The crystallographic part was supported by the Project 18-10504S of the Czech Science Foundation using instruments of the ASTRA lab established within the Operation program Prague Competitiveness Project CZ.2.16/3.1.00/24510.

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Authors and Affiliations

  1. Department of Chemistry, University of Zabol, P.O.Box, Zabol, 98613-35856, Iran

    Zohreh Razmara

  2. Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, 18221, Prague 8, Czech Republic

    Vaclav Eigner & Michal Dusek

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  1. Zohreh Razmara
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  2. Vaclav Eigner
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  3. Michal Dusek
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Correspondence to Zohreh Razmara.

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Razmara, Z., Eigner, V. & Dusek, M. Ultrasonic synthesis, crystal structure, luminescent, and magnetic properties of a new metal–organic complex based on Ce(IV)–Sr(II). Res Chem Intermed 45, 4335–4347 (2019). https://doi.org/10.1007/s11164-019-03834-z

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