Abstract
A series of CeO2 prepared with H2SO4 (C–S), H3PO4 (C–P) and H2SO4 + H3PO4 (C–P–S) were investigated in selective catalytic reduction of NOx with NH3. The sulfates contributed to the improvement of Brønsted (B) acid sites, while phosphates were prone to the enhancement of Lewis (L) acid sites, which could improve the catalytic activity. Furthermore, sulfates existed in the surface of C–P–S and C–S; phosphates occurred on the subsurface region or were highly dispersed on the surface of C–P–S and C–P. Besides, the nitrates adsorbed on the CeO2 and NH3 contacted with the sulfates, which followed the L–H mechanism at 200 °C on C–P–S and C–S. The adsorption and activation of NO and NH3 over C–P occurred at the same active sites, which obeyed the E–R mechanism at 200 °C. C–P–S possessed the best catalytic activity because of the appropriate surface acidity and redox property, and more than 80% conversion of NOx was obtained at 220–450 °C.
Graphical abstract
CeO2 modified by H2SO4 (C–S), H3PO4 (C–P) and H2SO4 + H3PO4 (C–P–S) was prepared and used for selective catalytic reduction of NOx by NH3. The presence of sulfate species over C–S and C–P–S contributed to the formation of surface acidity. CeO2 modified by phosphoric acid favored excellent oxidation ability.
Similar content being viewed by others
References
C. Niu, X.Y. Shi, F.D. Liu, K. Liu, L.J. Xie, Y. You, H. He, Chem. Eng. J. 294, 254 (2016)
L. Xu, X.S. Li, M. Crocker, Z.S. Zhang, A.M. Zhu, C. Shi, J. Mol. Catal. A: Chem. 378, 82 (2013)
T. Yu, J. Wang, M.Q. Shen, J.Q. Wang, W. Li, Chem. Eng. J. 264, 845 (2015)
W.C. Yu, X.D. Wu, Z.C. Si, D. Weng, Appl. Surf. Sci. 283, 209 (2013)
H. Tounsi, S. Djemal, C. Petitto, G. Delahay, Appl. Catal. B Environ. 107, 158 (2011)
Y.J. Kim, H.J. Kwon, I. Heo, I.S. Nam, B.K. Cho, J.W. Choung, M.S. Cha, G.K. Yeo, Appl. Catal. B Environ. 126, 9 (2012)
Z.M. Liu, S.X. Zhang, J.H. Li, L.L. Ma, Appl. Catal. B Environ. 144, 90 (2014)
N.Y. Topsøe, Science 265, 1217 (1994)
L. Chen, J.H. Li, M.F. Ge, Environ. Sci. Technol. 44, 9590 (2010)
K.Z. Li, J.H. Li, Appl. Catal. B Environ. 140, 483 (2013)
Y. Peng, R.Y. Qu, X.Y. Zhang, J.H. Li, Chem. Commun. 49, 6215 (2013)
L.S. Cheng, R.T. Yang, N. Chen, J. Catal. 164, 70 (1996)
Q.L. Zhang, Z.X. Song, P. Ning, X. Liu, H. Li, J.J. Gu, Catal. Commun. 59, 170 (2015)
G. Qi, R.T. Yang, Appl. Catal. B Environ. 44, 217 (2003)
C. Larese, M. López Granados, R. Mariscal, J.L.G. Fierro, P.S. Lambrou, A.M. Efstathiou, Appl. Catal. B Environ. 59, 13 (2005)
S.J. Yang, Y.F. Guo, H.Z. Chang, L. Ma, Y. Peng, Z. Qu, N.Q. Yan, C.Z. Wang, J.H. Li, Appl. Catal. B Environ. 136–137, 19 (2013)
Z.B. Wu, R.B. Jin, Y. Liu, H.Q. Wang, Catal. Commun. 9, 2217 (2008)
F.D. Liu, K. Asakura, H. He, W.P. Shan, X.Y. Shi, C.B. Zhang, Appl. Catal. B Environ. 103, 369 (2011)
Z.C. Si, D. Weng, X.D. Wu, Z.R. Ma, J. Ma, R. Ran, Catal. Today 201, 122 (2013)
Z.C. Si, D. Weng, X.D. Wu, R. Ran, Z.R. Ma, Catal. Commun. 17, 146 (2012)
S. Gao, X.B. Chen, H.Q. Wang, J.S. Mo, Z.B. Wu, Y. Liu, X.L. Weng, J. Colloid Interface Sci. 394, 515 (2013)
C. Larese, F.C. Galisteo, M.L. Granados, R. Mariscal, J. Fierro, M. Furió, R.F. Ruiz, Appl. Catal. B Environ. 40, 305 (2013)
F. Li, Y.B. Zhang, D.H. Xiao, D.Q. Wang, X.Q. Pan, X.G. Yang, Chem. Cat. Chem. 2, 1416 (2010)
F. Li, D.H. Xiao, Y.B. Zhang, D.Q. Wang, X.Q. Pan, X.G. Yang, Chin. J. Catal. 31, 938 (2010)
J. Yu, Z.C. Si, L. Chen, X.D. Wu, D. Weng, Appl. Catal. B Environ. 163, 223 (2015)
Z.C. Si, D. Weng, X.D. Wu, J. Yang, B. Wang, Catal. Commun. 11, 1045 (2010)
S.X. Yang, W.P. Zhu, Z.P. Jiang, Z.X. Chen, J.B. Wang, Appl. Surf. Sci. 252, 8499 (2006)
X. Gao, Y. Jiang, Y. Zhong, Z.Y. Luo, K.F. Cen, J. Hazard. Mater. 174, 734 (2010)
C.X. Liu, L. Chen, H.Z. Chang, L. Ma, Y. Peng, H. Arandiyan, J.H. Li, Catal. Commun. 40, 145 (2013)
J.C. Dupin, D. Gonbeau, P. Vinatier, A. Levasseur, Phys. Chem. Chem. Phys. 2, 1319 (2000)
Y.S. Eom, S.H. Jeon, T.A. Ngo, J. Kim, T.G. Lee, Catal. Lett. 121, 219 (2008)
L. Chen, J.H. Li, M.F. Ge, Chem. Eng. J. 170, 531 (2011)
X.J. Yao, Z. Wang, S.H. Yu, F.M. Yang, L. Dong, J. Mol. Catal. A: Chem. 542, 282 (2017)
L. Zhang, W.X. Zou, K.L. Ma, Y. Cao, Y. Xiong, S.G. Wu, C.J. Tang, F. Gao, L. Dong, J. Phys. Chem. C 119, 1155 (2015)
Z.M. Liu, S.X. Zhang, J.H. Li, J.Z. Zhu, L.L. Ma, Appl. Catal. B Environ. 158, 11 (2014)
Y. Jiang, X. Gao, Y.X. Zhang, W.H. Wu, H. Song, Z.Y. Luo, K.F. Cen, J. Hazard. Mater. 274, 270 (2014)
N.Y. Topsoe, H. Topsoe, J.A. Dumesic, J. Catal. 151, 226 (1995)
I. Nova, C. Ciardelli, E. Tronconi, D. Chatterjee, B. Bandl-Konrad, Catal. Today 114, 3 (2006)
W.S. Hu, Y.H. Zhang, S.J. Liu, C.H. Zheng, X. Gao, I. Nova, E. Tronconi, Appl. Catal. B Environ. 206, 449 (2017)
H. Zhang, Y.G. Zou, Y. Peng, Chin. J. Catal. 38, 160 (2017)
X.S. Du, X. Gao, K.Z. Qiu, Z.Y. Luo, K.F. Cen, J. Phys. Chem. C 119, 1905 (2015)
Y. Peng, J.H. Li, L. Chen, J.H. Chen, J. Han, H. Zhang, W. Han, Environ. Sci. Technol. 46, 2864 (2012)
T. Yi, Y.B. Zhang, J.W. Li, X.G. Yang, Chin. J. Catal. 37, 300 (2016)
R.Y. Qu, X. Gao, K.F. Cen, J.H. Li, Appl. Catal. B Environ. 142–143, 290 (2013)
Acknowledgements
This work is supported by the National Natural Science Foundation of China (Nos. 21307047 and 51509083) and Henan Key Scientific Research Projects (Nos. 18A610002 and 16A610005).
Author information
Authors and Affiliations
Corresponding authors
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Song, Z., Wang, J., Zhang, Q. et al. Comparison of sulfuric acid- or phosphoric acid-modified CeO2 and the influence of surface acidity and redox property on its activity toward NH3-SCR. Res Chem Intermed 45, 645–661 (2019). https://doi.org/10.1007/s11164-018-3635-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11164-018-3635-2