Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in γ-valerolactone

  • Feng Huang
  • Wenzhi Li
  • Tingwei Zhang
  • Dawei Li
  • Qiyu Liu
  • Xifeng Zhu
  • Longlong Ma
Article
  • 13 Downloads

Abstract

A carbonaceous solid acid catalyst with high strong-acid density was synthesized by facile functionalization of a biomass-derived mesoporous carbon with benzenesulfonic acid. The catalyst was characterized by using Fourier transform infrared spectroscopy, elemental analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and N2 adsorption–desorption. The carbonaceous solid catalyst containing Brønsted acid sites was used for the production of 5-hydroxymethylfurfural (HMF) from hexoses such as fructose, glucose, and cellulose in γ-valerolactone (GVL)-H2O mixture. By reaction at 130 °C for 20 min using fructose as a feedstock, an HMF yield 78.1% was achieved. The catalytic performance of the catalyst in conversion of fructose into HMF hardly changed over seven cycles, demonstrating that the catalyst had excellent recyclability. The yields of HMF derived from glucose and cellulose reached 33.2 and 22.5%, respectively, whereas those of total furans were 42.1 and 33.7%, respectively. The proposed reaction system was promising in transforming biomass-based carbohydrates into fine chemicals, given the use of green functionalization methods, the utilization of sustainable biomass-derived carbon precursor and solvents, catalyst with high acid density, and the availability of high HMF yield.

Keywords

Carbohydrate Fructose Glucose 5-Hydroxymethylfurfural γ-Valerolactone Carbon solid acid 

Notes

Acknowledgements

This study was financially supported by the State Key Program of National Natural Science Foundation of China (51536009), Science and Technological Fund of Anhui Province for Outstanding Youth (1508085J01) and the National Key Technology R&D Program of China (No. 2015BAD15B06).

Compliance with ethical standards

Conflict of interest

The authors declared that they have no conflict of interest.

Supplementary material

11164_2018_3432_MOESM1_ESM.docx (184 kb)
Supplementary material 1 (DOCX 183 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • Feng Huang
    • 1
  • Wenzhi Li
    • 1
  • Tingwei Zhang
    • 1
  • Dawei Li
    • 2
  • Qiyu Liu
    • 1
  • Xifeng Zhu
    • 1
  • Longlong Ma
    • 3
  1. 1.Department of Thermal Science and Energy EngineeringUniversity of Science and Technology of ChinaHefeiPeople’s Republic of China
  2. 2.State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum (East China)QingdaoPeople’s Republic of China
  3. 3.CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy ConversionChinese Academy of SciencesGuangzhouPeople’s Republic of China

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