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Research on Chemical Intermediates

, Volume 44, Issue 7, pp 4503–4518 | Cite as

Facile synthesis of CoNi2S4/graphene nanocomposites as a high-performance electrode for supercapacitors

  • Jingjing Lin
  • Song Yan
  • Ping Liu
  • Xing Chang
  • Lu Yao
  • Hualin Lin
  • Deli Lu
  • Sheng Han
Article

Abstract

CoNi2S4/graphene nanocomposites were synthesized by a simple solvothermal method and used as supercapacitor electrodes. CoNi2S4 nanoparticles were doped in graphene layers, which is favorable for improving electrochemical performances of the as-prepared materials. The resulting electrochemical performance of CoNi2S4/graphene nanocomposite electrodes possessed pseudocapacitive behavior with high specific capacitance (1621 F g−1 at 0.5 A g–1), good rate capability (76.7% capacitance retention when reaching 10 A g–1) and outstanding cycling stability (no capacitance loss after 2500 charge–discharge cycles at 5 A g–1). In addition, as the positive electrode of an asymmetric supercapacitor, the material also shows a high specific capacitance of 126.6 F g–1 at 0.5 A g–1, good cycle stability with capacitance retention of 87.4% after 5000 cycles and the highest energy density of 39.56 W h kg–1 at the power density of 374.8 W kg–1.

Keywords

CoNi2S4/graphene supercapacitors High specific capacitance Asymmetric electrode 

Notes

Acknowledgements

This work was supported from the National Natural Science Foundation of China (Project Numbers 51641208 and 21606151), Shanghai Association for Science and Technology Achievements Transformation Alliance Program (Project Numbers LM201680 and LM201559), Shanghai Excellent Technology Leaders Program (Project Number 17XD1424900), Shanghai Leading Talent Program (Project Number 017), Science and Technology Commission of Shanghai Municipality Project (Project Numbers 14520503200 and ZX2016-7). Collaborative Innovation Fund of SIT, XTCX2015-9.

Supplementary material

11164_2018_3400_MOESM1_ESM.docx (907 kb)
Supplementary material 1 (DOCX 906 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Chemical and Environmental EngineeringShanghai Institute of TechnologyShanghaiPeople’s Republic of China

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