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Research on Chemical Intermediates

, Volume 44, Issue 7, pp 4397–4413 | Cite as

Copper incorporated mesoporous materials: synthesis, characterization and catalytic activity in benzaldehyde reduction

  • O. Zekri
  • A. Saadi
  • F. Launay
  • C. Calers
  • C. Rabia
Article
  • 45 Downloads

Abstract

Copper substituted mesoporous silica materials (Cu–HMS-n), with a variety of Si/Cu atomic ratios (n) ranging from 50 to 100, were synthesized by the one-pot sol–gel method using dodecylamine as template. These materials were characterized by X-ray diffraction, N2 adsorption-desorption, transmission electron microscopy, ultraviolet and visible diffuse reflectance spectroscopy, H2 temperature-programmed reduction, inductively coupled plasma-optical emission spectrometry, thermal analysis and X-ray photoelectron spectroscopy. All the samples showed worm-like mesoporous structures with surface areas higher than 700 m2 g−1 and pore volumes higher than 0.75 cm3 g−1. The catalytic activity of these materials in the reduction of benzaldehyde was evaluated. Effects of the Si/Cu atomic ratio in the catalyst and the influence of time and reaction temperature on the catalytic activity were investigated. Best catalytic performance was obtained with Cu–HMS-50 with a benzaldehyde conversion of 56% and a selectivity of 28% to benzyl alcohol.

Keywords

Cu-incorporating mesoporous materials Copper Benzaldehyde Benzyl alcohol Hydrogenation 

Notes

Acknowledgements

The authors thank the Ministry of Scientific Research (Algeria) for the research grant and the LRS group (Surface Reactivity Laboratory) at UMR CNRS 7197 at Pierre et Marie Curie University Paris VI (France) for their collaboration.

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Laboratoire du Gaz naturel, Faculté de ChimieUniversité des Sciences et Technologie Houari Boumediene (USTHB)AlgerAlgeria
  2. 2.CNRS, Laboratoire de Réactivité des Surface, LRSSorbonne UniversitéParisFrance

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