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Research on Chemical Intermediates

, Volume 44, Issue 7, pp 4245–4258 | Cite as

Design and synthesis of novel natural clinoptilolite-MnFe2O4 nanocomposites and their catalytic application in the facile and efficient synthesis of chalcone derivatives through Claisen-Schmidt reaction

  • Reza Aryan
  • Noshin Mir
  • Hamid Beyzaei
  • Amin Kharade
Article
  • 105 Downloads

Abstract

A series of three novel nanocomposites were prepared by modifying the surface of natural clinoptilolite using various amounts of manganese ferrite (MnFe2O4) nanoparticles. These manganese ferrite-modified nanocomposites (MFO–NC) were fully characterized by XRD, FT-IR, EDX, VSM and TEM analyses. One of these novel nanocomposites with 40 wt% of manganese ferrite in clinoptilolite (MFO–NC-3) showed a strong catalytic behavior in the aldol-type Claisen–Schmidt reaction for the synthesis of chalcones. A strong catalytic synergy was observed between nano-MnFe2O4 particles and natural clinoptilolite in the structure of these nanocomposites. The products with a broad range of substituents on the reactants were efficiently obtained under room-temperature conditions within relatively short reaction times with good to excellent yields in the presence of one of the prepared MFO–NC nanocomposites. This nanocomposite also showed a strong stability and substantial reusability in the synthesis of chalcones.

Keywords

Heterogeneous catalysis Manganese ferrite Natural clinoptilolite Nanocomposite Chalcones Claisen–Schmidt reaction 

Notes

Acknowledgements

The corresponding author gratefully acknowledges helpful scientific consultations from Dr. Masoomeh Nojavan. Partial financial support of this work by University of Zabol Research Council and the Dean of the Faculty of Science are also appreciated.

Supplementary material

11164_2018_3366_MOESM1_ESM.docx (1021 kb)
Supplementary material 1 (DOCX 1021 kb)

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© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceUniversity of ZabolZabolIran

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