Research on Chemical Intermediates

, Volume 44, Issue 7, pp 4103–4117 | Cite as

Ferric (hydr)oxide/mesoporous carbon composites as Fenton-like catalysts for degradation of phenol

  • Meng Ren
  • Xufang Qian
  • Mengyuan Fang
  • Dongting Yue
  • Yixin Zhao
Article

Abstract

Ferric (hydr)oxide (Fhy) is the most widespread iron compound in natural environments which participates in the photochemical process and production of reactive oxygen species in soil and sediment. Three typical Fhy/mesoporous carbon (Fhy/MC) composites in which Fhy nanoparticles (NPs), nanorods (NRs) and/microrods (MRs) crystallized within and/or attached on MC materials were prepared by a hydrothermal process at 70 °C. We explored the performance of Fenton-like oxidation of phenol and mineralization in the presence of H2O2 at a near-neutral pH value (pH = 5). The results showed that Fhy-NP/MC composite in which Fhy NPs were encapsulated in MC frameworks showed the highest catalytic performance due to the plentiful active surface available in comparison with the other two Fhy/MC composites containing larger Fhy NRs or MRs. The recycling test showed Fhy-NP/MC composite retained the high catalytic activity after 5 runs. Visible light irradiation can obviously promote the phenol oxidation performance and the decomposition of H2O2 due to the increased production amount of HO· than that in dark conditions. Hydroxyl radical measurement also revealed that the synergistic effect between Fhy and MC.

Graphical Abstract

Keywords

Ferric (hydr)oxide Mesoporous carbon Heterogenous Fenton Composite materials Phenol 

Notes

Acknowledgements

This work is supported by the National Natural Science Foundation of China (21507083, 21777097), Shanghai Government (15PJ1404000), and Key Laboratory of Resource Chemistry, Ministry of Education.

Supplementary material

11164_2018_3358_MOESM1_ESM.docx (422 kb)
Supplementary material 1 (DOCX 417 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Environmental Science and EngineeringShanghai Jiao Tong UniversityShanghaiChina

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