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Three-component synthesis of alkylammonium 4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydropyrrol-1-ides

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Abstract

This study presents a three-component reaction between malononitrile dimer, α-diketone and aliphatic amine that leads to the formation of previously undescribed alkylammonium 4-cyano-5-(dicyanomethylene)-2-hydroxy-2,3-dimethyl-2,5-dihydropyrrol-1-ides. This reaction is a novel approach for modification of donor–acceptor chromophores containing the buta-1,3-diene-1,1,3-tricarbonitrile moiety.

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Acknowledgements

This work was supported by Russian Foundation for Basic Research, Grant No. 16-33-60156 mol_a_dc. The XRD study was carried out using the equipment purchased from the funds of the Program of development of Moscow University and within the framework of the Agreement on collaboration between the Chemical Department of the Lomonsov Moscow State University and the Chemical-Pharmaceutical Department of the I.N. Ulyanov Chuvash State University.

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Authors and Affiliations

  1. Ulyanov Chuvash State University, Moskovsky pr., 15, Cheboksary, Russia, 428015

    Sergey V. Fedoseev, Mikhail Yu. Belikov, Mikhail Yu. Ievlev & Oleg V. Ershov

  2. Lomonosov Moscow State University, Leninskie gori, 1, Moscow, Russia, 119991

    Viktor A. Tafeenko

Authors
  1. Sergey V. Fedoseev
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  2. Mikhail Yu. Belikov
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  3. Mikhail Yu. Ievlev
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  4. Oleg V. Ershov
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  5. Viktor A. Tafeenko
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Corresponding author

Correspondence to Oleg V. Ershov.

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Fedoseev, S.V., Belikov, M.Y., Ievlev, M.Y. et al. Three-component synthesis of alkylammonium 4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydropyrrol-1-ides. Res Chem Intermed 44, 3565–3579 (2018). https://doi.org/10.1007/s11164-018-3325-0

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