Novel probes based on coumarin-bisdithiocarbamate system for selective recognition of Ag(I) in aqueous solution

  • Guo Feng Chen
  • Lin Liu
  • Jiu Li Wu
  • Suo Juan Wu
  • Bao Hua Chen
Article
  • 16 Downloads

Abstract

Two novel fluorescent probes (C1, C2), comprising a coumarin moiety as fluorophore and a pair of dithiocarbamates as recognition sites, were designed and synthesized as fluorescent probes for Ag+. The probes exhibited high selectivity for Ag+ with fluorescence enhancement (FE) in CH3CN/4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid (HEPES) (1:9, v/v, pH 7.38); the selectivity was not affected by other metal ions. The binding ratio of C2–Ag+ complex was determined to be 1:1 according to the Job plot and mass spectroscopy (MS) data. The association constant Ka of Ag+ with C2 was 1.6 × 104 M−1. These probes could be applied for monitoring of Ag+ in aqueous solution in the pH range of 5.0–8.0, with calculated detection limit of 0.27 μM.

Keywords

Fluorescent probe Coumarin Dithiocarbamate Ag+ 

Notes

Acknowledgements

This work was supported by Youth Foundation of Hebei Province Department of Education (QN2015039) and the Foundation of Hebei University (no. 799207217002).

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Copyright information

© Springer Science+Business Media B.V. 2017

Authors and Affiliations

  • Guo Feng Chen
    • 1
  • Lin Liu
    • 1
  • Jiu Li Wu
    • 1
  • Suo Juan Wu
    • 1
  • Bao Hua Chen
    • 2
  1. 1.Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Environmental ScienceHebei UniversityBaodingPeople’s Republic of China
  2. 2.College of Pharmaceutical SciencesHebei UniversityBaodingPeople’s Republic of China

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