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The catalytic effect of Al-KIT-5 and KIT-5-SO3H on the conversion of fructose to 5-hydroxymethylfurfural

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An Erratum to this article was published on 02 June 2017

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Abstract

The aim of this work is to study the production of hydroxymethylfurfural (HMF) from fructose using heterogenous catalysts based on KIT-5. For this propose, Al-KIT-5 and KIT-5-SO3H as the Lewis and Bronsted catalysts were prepared and were characterized using different techniques such as FT-IR, SEM, EDS, TEM, BET, TGA and elemental analysis. With the use of Al-KIT-5 as the catalyst, the appropriate reaction temperature and time were 135 °C and 60 min, respectively. Moreover, with the use of KIT-5-SO3H as the catalyst, the proper reaction conditions were found to be 125 °C and 45 min, respectively. In addition, the corresponding amounts of catalyst weight were 40 and 50 mg for KIT-5-SO3H and Al-KIT-5, respectively. Under these conditions, the conversion of fructose was 93.9 and 88.3%, respectively. These results indicated that, due to its Bronsted acid nature, the KIT-5-SO3H catalyst showed better results when 40 mg catalyst was used at 125 °C for 45 min in DMSO as the solvent. Both catalysts could be recycled and reused several times.

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  • 02 June 2017

    An erratum to this article has been published.

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Acknowledgements

The authors would like to thank Isfahan University of Technology (Iran) for the financial support (Research Council Grant). In addition, authors would like to thank the Iranian National Science Foundation (INSF) for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Isfahan University of Technology, Isfahan, 84154-83111, Iran

    Alireza Najafi Chermahini, Hamid Hafizi, Nikzad Andisheh, Mohammad Saraji & Ali Shahvar

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  1. Alireza Najafi Chermahini
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  2. Hamid Hafizi
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  3. Nikzad Andisheh
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  4. Mohammad Saraji
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  5. Ali Shahvar
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Correspondence to Alireza Najafi Chermahini.

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An erratum to this article is available at https://doi.org/10.1007/s11164-017-2991-7.

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Najafi Chermahini, A., Hafizi, H., Andisheh, N. et al. The catalytic effect of Al-KIT-5 and KIT-5-SO3H on the conversion of fructose to 5-hydroxymethylfurfural. Res Chem Intermed 43, 5507–5521 (2017). https://doi.org/10.1007/s11164-017-2943-2

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