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Influence of chlorine substitution on the crystal structures of diaryl oxalate

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Abstract

Three diaryl oxalate derivatives, bis(4-chlorophenyl)oxalate, bis(2, 6-dichlorophenyl)oxalate and bis(2, 4, 6-trichlorophenyl)oxalate, have been synthesized and characterized via X-ray single crystal diffraction, differential scanning calorimetry, thermogravimetric analysis and infrared spectra, for the purpose of studying the influence of chlorine substitution on the crystal structures of diaryl oxalate. This work has demonstrated that, depending on the position and number, chlorine substitution will influence the molecular geometries and stacking modes of diaryl oxalate by tuning the types and numbers of intermolecular interactions.

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Acknowledgments

This work has been supported by the National Natural Science Foundation of China (Project 21371031) and the International S&T Cooperation program of China (2015DFG42240).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 210096, People’s Republic of China

    Dong-En Wu, Yang-Hui Luo, Ting-Ting Li, Man-Ning Wang, Gao-Ju Wen & Bai-Wang Sun

  2. College of Cheng-xian, Southeast University, Nanjing, 210088, People’s Republic of China

    Chang-Po Fan

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  1. Dong-En Wu
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Correspondence to Bai-Wang Sun.

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Wu, DE., Luo, YH., Li, TT. et al. Influence of chlorine substitution on the crystal structures of diaryl oxalate. Res Chem Intermed 43, 1591–1607 (2017). https://doi.org/10.1007/s11164-016-2717-2

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  • DOI: https://doi.org/10.1007/s11164-016-2717-2

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