Abstract
In this study, activation of pistachio shell char was investigated by chemical, physical and combined activation experimentally using a TGA instrument and lab scale reactor. The effects of operating conditions such as activation time, temperature and impregnation ratio in the activation methods were studied via the weight loss and iodine number of the samples. The results showed that combined activation is the premium activation method. In addition, in this method. a temperature of 800 °C, a dwell time of 45 min and an impregnation ratio of 50 % are the optimum conditions which give a product with an iodine number of 2433 mg/g and a weight loss 52 %. A high iodine number of this activated carbon was developed at a moderate temperature and dwell time, and the weight loss confirms the advantages of the combined activation method. The products were characterized by SEM and FTIR analyses.
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E. Schröder, K. Thomauske, C. Weber, A. Hornung, V. Tumiatti, J. Anal. Appl. Pyrol. 79, 1–2 (2007)
J. Laine, A. Calafat, Carbon 29, 7 (1991)
H. Dolas, O. Sahin, C. Saka, H. Demir, Chem. Eng. J. 166, 1 (2011)
M.T. Izquierdo, A. Martinez, B. de Yuso, M. Rubio, R. Pino, Biomass Bioenergy 351, 1235 (2011)
M. Ozdemir, T. Bolgaz, C. Saka, O. Sahin, Anal. Appl. Pyrol. 92, 1 (2011)
Z. Hu, M.P. Srinivasan, Y. Ni, Carbon 39, 6 (2001)
O. Sahin, C. Saka, Bioresour. Technol. 136, 163–168 (2013)
C. Saka, Anal. Appl. Pyrol. 95, 1 (2012)
M. Özmak, Ph.D. Thesis in Chemical Engineering, Ankara University, Ankara, Turkey (2010)
M.A. Yahya, Z. Al-Qodah, C.W.Z. Ngah, Renew. Sust. Energy Rev. 46, 218–235 (2015)
H. Kamandari, H. Hashemipour, L. Saeednia, H. Najarzade, Res. Chem. Intermed. 40, 2 (2014)
H. Kamandari, H. Hashemipour, H. Najarzade, Z. Eksiri, Res. Chem. Intermed. 41, 1 (2015)
M. Jagtoyen, F. Derbyshire, Carbon 36, 7–8 (1997)
M.J. Ahmed, J. Eng. 17, 311–323 (2011)
M. Ozdemir, T. Bolgaz, C. Saka, O. Sahin, Anal. Appl. Pyrol 92, 1 (2011)
S.J. Allen, L. Whitten, G. McKay, Dev. Chem. Eng. Miner. Process. 5, 231–261 (1998)
H. Muhlen, K.H. Van Heek, W. Patrick Jr., Porosity in carbons: Characterization and Applications (Halsted Press, London, 1995)
B. Viswanathan, P. Indra Neel, T.K. Varadarajan, Methods of Activation and Specific Applications of Carbon Materials, 1st edn. (National Centre for Catalysis Research, Indian Institute of Technology, Madras, 2009), pp. 19–26
T. Budinova, E. Ekinci, F. Yardim, A. Grimm, E. Björnbom, V. Minkova, M. Goranova, Fuel Process. Technol. 87, 10 (2006)
IUPAC (International Union of Pure and Applied Chemistry Physical Chemistry Division Commission on Colloid and Surface Chemistry Including Catalysis(, Pure. Appl. Chem. 57, 4 (1985(
A.N.A. El-Hendawy, Appl. Surf. 255, 6 (2009)
C.A. Nunes, M.C. Guerreiro, Quim Nova 34, 3 (2011)
A.C. Lua, T. Yang, J. Colloid Interface Sci 255, 6 (2009)
A.C. Lua, T. Yang, J. Colloid Interface Sci. 290, 2 (2005)
A.C. Lua, T. Yang, Colloid Interface Sci. 274, 2 (2004)
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Banivaheb, S., Hashemipour, H. Investigation on effects of operating conditions in combined activation of char to develop the pore structure. Res Chem Intermed 43, 1513–1527 (2017). https://doi.org/10.1007/s11164-016-2712-7
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DOI: https://doi.org/10.1007/s11164-016-2712-7