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Heterogeneity in optimized solid-state synthesis of metavanadate AVO3 (A = Rb, Cs)

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Abstract

Methanol was used to optimize the solid-state synthesizing method of alkali metavanadates AVO3 (A = Rb, Cs) for the first time and the benefits are discussed. Due to the optimization, four kinds of heterogeneous AVO3 compounds, white CsVO3 [CsVO3 (W)], yellow CsVO3 [CsVO3 (Y)], white RbVO3 [RbVO3 (W)], and red RbVO3 [RbVO3 (R)], could be easily obtained. The colored compounds CsVO3 (Y) and RbVO3 (R) are reported for the first time and their synthetic process has been summarized, while their crystal structure, morphology, vibration spectroscopy, photoluminescence, moisture adsorption and thermodynamic properties were measured and compared to white compounds. The differences in properties of CsVO3 (Y) and RbVO3 (R) were hypothesized as the oriented growth and induced defects. All four AVO3 compounds were excellent white-light-emitting phosphors, and CsVO3 (Y) and RbVO3 (R), with additional waterproofness, suggested much more practical value.

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Acknowledgments

This study was financially supported by the Science and Technology Commission of Shanghai Municipality (STCSM, Nos. 14DZ2261203, 5157021410).

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Authors and Affiliations

  1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Dingxi 1295, Changning, Shanghai, 200050, China

    Guangyao Sun, Wenjing Li, Shidong Ji, Xun Cao & Ping Jin

  2. Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA, 94720, USA

    Xun Cao

  3. Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology, Nagoya, 463-8560, Japan

    Ping Jin

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  1. Guangyao Sun
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  2. Wenjing Li
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Correspondence to Ping Jin.

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Sun, G., Li, W., Ji, S. et al. Heterogeneity in optimized solid-state synthesis of metavanadate AVO3 (A = Rb, Cs). Res Chem Intermed 43, 341–352 (2017). https://doi.org/10.1007/s11164-016-2625-5

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