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Sulfamic acid-catalyzed, environmentally benign synthesis of bis-tetronic acids at ambient temperature

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Abstract

An enviro-economic protocol has been described for the synthesis of bis-tetronic acids by pseudo-three-component condensation between aldehydes/isatins and tetronic acid using sulfamic acid as a solid acid catalyst. Easy commercial availability of the catalyst at extremely low cost, excellent yields and avoidance of conventional purification procedures are the main merits of this energy efficient protocol.

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Acknowledgments

Authors KSP and UVD are grateful to UGC, New Delhi, for financial assistance [F. No. 43-221/2014 (SR)]. We are also grateful to DST, New Delhi, for financial assistance to the Department of Chemistry, Shivaji University Kolhapur, under DST–FIST program.

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Authors and Affiliations

  1. Organic Chemistry Division, Department of Chemistry, Shivaji University, Kolhapur, 416004, India

    Kapil S. Pandit & Uday V. Desai

  2. Polymer Science and Engineering Division, CSIR, National Chemical Laboratory, Pune, 411008, India

    Prakash P. Wadgaonkar

  3. Department of Chemistry, Savitribai Phule Pune University, Pune, 411007, India

    Kisan M. Kodam

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  1. Kapil S. Pandit
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Correspondence to Uday V. Desai.

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Pandit, K.S., Desai, U.V., Wadgaonkar, P.P. et al. Sulfamic acid-catalyzed, environmentally benign synthesis of bis-tetronic acids at ambient temperature. Res Chem Intermed 43, 141–152 (2017). https://doi.org/10.1007/s11164-016-2611-y

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