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The crystal structure and thermal analysis of ZTO and its solvent adducts

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Abstract

4,4-azo-bis(1,2,4-triazol-5-one) (ZTO) and its solvent adducts have been reported, and the single crystal X-ray measurements indicated that the ZTO crystals appeared as a monoclinic system with space group P2(1)/c, while ZTO·2H2O and ZTO·2DMF displayed as monoclinic with space group P2(1)/n and triclinic with space group Pī, respectively. In addition, the thermal decomposition process of the three crystals was studied by thermogravimetric differential analysis (TG-DTA), and the result showed that only one exothermic peak was found in each case of ZTO, ZTO·2H2O, and ZTO·2DMF, and the peak temperature (T p) are observed at 292.36, 291.82, and 272.73 °C, respectively.

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Authors and Affiliations

  1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing, People’s Republic of China

    Jiaping Zhu, Shaohua Jin, Yuehai Yu, Lijie Li, Shusen Chen & Qinghai Shu

Authors
  1. Jiaping Zhu
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  2. Shaohua Jin
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  3. Yuehai Yu
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  4. Lijie Li
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  5. Shusen Chen
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  6. Qinghai Shu
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Corresponding author

Correspondence to Qinghai Shu.

Additional information

The crystallographic information file for ZTO and its solvent adducts have been deposited by us in the Cambridge structure database (CCDC 1048057, 1048054, and 1048061). These data can be obtained free of charge via www.ccdc.cam.ac.uk.

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Zhu, J., Jin, S., Yu, Y. et al. The crystal structure and thermal analysis of ZTO and its solvent adducts. Res Chem Intermed 42, 4333–4340 (2016). https://doi.org/10.1007/s11164-015-2278-9

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