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Palladium complexes bearing the dipyridyl ligand: synthesis, structural studies, and use in the Heck reaction

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Abstract

Two new palladium complexes derived from the di(2-pyridinyl)methanone N-(2-pyridinyl)hydrazone (DPMNPH) ligand are reported. The compounds were characterized by elemental analysis, spectroscopic studies, and, for the DPMNPH ligand, single-crystal X-ray diffraction analysis. The DPMNPH ligand crystallized as orthorhombic with the space group P212121. The H1 atom is intramolecularly bonded to the pyridinic N4 with N1–H1 = 0.92(3) Å, H1···N4 = 1.87(2) Å, N1···N4 = 2.615(2) Å, and N1–H1···N4 = 137(2)°. Both complexes were excellent catalysts in the Heck reaction in the presence of base.

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Acknowledgments

The authors would like to extend their sincere appreciation to the Dean of Scientific Research at King Saud University for funding this work through research group number RG -1435-091.

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Correspondence to Mohammad Azam.

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Warad, I., Azam, M., Al-Resayes, S.I. et al. Palladium complexes bearing the dipyridyl ligand: synthesis, structural studies, and use in the Heck reaction. Res Chem Intermed 42, 379–389 (2016). https://doi.org/10.1007/s11164-015-2256-2

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