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Synthesis and characterization of a novel nano-Fe3O4-copoly[(styrene/acrylic acid)/grafted ethylene oxide and its application as a magnetic and recyclable phase-transfer catalyst in the preparation of β-azido alcohols and β-nitro alcohols

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Abstract

A facile method was developed for the synthesis of β-azido alcohols and β-nitro alcohols in the presence of a novel nano-Fe3O4-copoly[(styrene/acrylic acid)/grafted ethylene oxide (nano-Fe3O4-PS-Co-[PAA-g-PEG]) as a phase-transfer catalyst in water. The catalyst was characterized with IR, SEM, and TGA. This procedure offers several advantages, including excellent regioselectivity, high yields, short reaction times, a recyclable catalyst, easy separation of the catalyst through an external magnet, and easy workup .

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Acknowledgments

We are grateful to the Research Council of Shahid Chamran University for financial support.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Sciences, Shahid Chamran University, 61357-4-3169, Ahvaz, Iran

    Ali Reza Kiasat & Mina Daei

  2. ACECR-Production Technology Research Institute, Ahvaz, Iran

    Seyyed Jafar Saghanezhad

Authors
  1. Ali Reza Kiasat
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  2. Mina Daei
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  3. Seyyed Jafar Saghanezhad
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Correspondence to Ali Reza Kiasat.

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Kiasat, A.R., Daei, M. & Saghanezhad, S.J. Synthesis and characterization of a novel nano-Fe3O4-copoly[(styrene/acrylic acid)/grafted ethylene oxide and its application as a magnetic and recyclable phase-transfer catalyst in the preparation of β-azido alcohols and β-nitro alcohols. Res Chem Intermed 42, 581–594 (2016). https://doi.org/10.1007/s11164-015-2043-0

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