Skip to main content
SpringerLink
Log in

Influence of organic corrosion inhibitors on the corrosion performance of organic–inorganic hybrid coatings applied on aluminium alloy

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The proposed work aims to develop and study sol–gel derived anticorrosion films for aluminium. To further improve performance of these films, organic corrosion inhibitors were incorporated into the films. The organic–inorganic hybrid films with and without corrosion inhibitors were deposited on an aluminium substrate by dip coating. The films were characterized by electrochemical impedance spectroscopy (EIS), DC polarisation techniques, and neutral salt spray test to evaluate their anticorrosion properties. This study shows that very low and very high MBT concentrations deteriorate the corrosion performance of coatings, and consequently, there is an optimum concentration of MBT. EIS results revealed a higher corrosion inhibitive activity of 2-mercaptobenzothiazole (MBT) compared to that of 2-amino-5-methylthiazole and 1,2,3 benzotriazole.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. S. Hong-wei, L. Fu-chun, H. En-hou, S. Ming-cheng, Chin. J. Aeronaut. 19, 106 (2006)

    Google Scholar 

  2. B.Y. Johnson, J. Edington, M.J. O’Keefe, Mater. Sci. Eng. A 361, 225 (2003)

    Article  Google Scholar 

  3. Lj S. Zivkovic, B.V. Jegdic, J.P. Popic, J.B. Bajat, V.B. Miskovic-Stankovic, Prog. Org. Coat. 76, 1387 (2013)

    Article  CAS  Google Scholar 

  4. R.M. Park, J.F. Bena, L.T. Stayner, R.J. Smith, H.J. Gibb, P.S.J. Lees, Risk Anal. 24, 1099 (2004)

    Article  Google Scholar 

  5. J.D. Zhang, S.K. Li, J. Occup. Environ. Med. 39, 315 (1997)

    Article  CAS  Google Scholar 

  6. A. Baral, R. Engelken, W. Stephens, J. Farris, R. Hannigan, Arch. Environ. Contam. Toxicol. 50, 496 (2006)

    Article  CAS  Google Scholar 

  7. M. Fallet, H. Mahdjoub, B. Gautier, J. Bauer, J. Non-Cryst. Solids, 293, 527 (2001)

  8. C.J. Brinker, G.W. Scherer, Sol–Gel Science: The Physics and Chemistry of Sol–Gel Processing (Academic Press, London, 1990)

    Google Scholar 

  9. A.A. Younis, W. Ensinger, M.M.B. El-Sabbah, R. Holze, Mater. Corros. 64, 276 (2013)

    Article  CAS  Google Scholar 

  10. L.S. Kasten, J.T. Grant, N. Grebasch, Surf. Coat. Technol. 140, 11 (2001)

    Article  CAS  Google Scholar 

  11. J. Wei-Gang, H. Ji-Ming, L. Liang, Z. Jian-Qing, C. Chu-Nan, Prog. Org. Coat. 57, 439 (2006)

    Article  Google Scholar 

  12. M.L. Zheludkevich, I.M. Salvado, M.G.S. Ferreira, J. Mater. Chem. 15, 5099 (2005)

    Article  CAS  Google Scholar 

  13. L.M. Palomino, P.H. Suegama, I.V. Aoki, M.F. Montemor, H.G. De Melo, Corros. Sci. 51, 1238 (2009)

    Article  CAS  Google Scholar 

  14. D. Raps, T. Hack, J. Wehr, M.L. Zheludkevich, A.C. Bastos, M.G.S. Ferreira, O. Nuyken, Corros. Sci. 51, 1012 (2009)

    Article  CAS  Google Scholar 

  15. A.C. Balaskas, I.A. Kartsonakis, D. Snihirova, M.F. Montemor, G. Kordas, Prog. Org. Coat. 72, 653 (2011)

    Article  CAS  Google Scholar 

  16. M. Mahdavian, S. Ashhari, Prog. Org. Coat. 68, 259 (2010)

    Article  CAS  Google Scholar 

  17. A.N. Khramov, N.N. Voevodin, V.N. Balbyshev, R.A. Mantz, Thin Solid Films 483, 191 (2005)

    Article  CAS  Google Scholar 

  18. A.N. Khramov, N.N. Voevodin, V.N. Balbyshev, M.S. Donley, Thin Solid Films 447–448, 549 (2004)

    Article  Google Scholar 

  19. H. Yang, W.J. van Ooij, Prog. Org. Coat. 50, 149 (2004)

    Article  CAS  Google Scholar 

  20. D.M. Evaggelos, A.K. Ioannis, C.K. George, Prog. Org. Coat. 73, 142 (2012)

    Article  Google Scholar 

  21. N.P. Tavandashti, S. Sanjabi, T. Shahrabi, Mater. Corros. 62, 411 (2011)

    Article  Google Scholar 

  22. P.C. Rajath Varma, B. Duffy, J. Cassidy, Surf. Coat. Technol. 204, 277 (2009)

    Article  Google Scholar 

  23. G. Chawada, B.Z. Dholakiya, Res. Chem. Intermed. (2013). doi:10.1007/s11164-013-1479-3

    Google Scholar 

  24. D. Battocchi, A.M. Simoes, D.E. Tallman, G.P. Bierwagen, Corros. Sci. 48, 1292 (2006)

    Article  CAS  Google Scholar 

  25. J.H. Osborne, K.Y. Blohowaik, S.R. Taylor, C. Hunter, G. Bierwagon, B. Carlson, D. Bernard, M.S. Donely, Prog. Org. Coat. 41, 217 (2001)

    Article  CAS  Google Scholar 

  26. E.M. Sherif, S.M. Park, Electrochim. Acta 51, 1313 (2006)

    Article  CAS  Google Scholar 

  27. M.S. Donley, R.A. Mantz, A.N. Khramov, Prog. Org. Coat. 47, 401 (2003)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Applied Chemistry Department, S. V. National Institute of Technology, Surat, 395007, Gujarat, India

    Gopal Chawada & Bharatkumar Z. Dholakiya

Authors
  1. Gopal Chawada
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Bharatkumar Z. Dholakiya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bharatkumar Z. Dholakiya.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chawada, G., Dholakiya, B.Z. Influence of organic corrosion inhibitors on the corrosion performance of organic–inorganic hybrid coatings applied on aluminium alloy. Res Chem Intermed 42, 545–557 (2016). https://doi.org/10.1007/s11164-015-2040-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-015-2040-3

Keywords

Search

Navigation