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Extraordinary catalytic activity of a Keplerate-type giant nanoporous isopolyoxomolybdate in the synthesis of 1,8-dioxo-octahydroxanthenes and 1,8-dioxodecahydroacridines

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Abstract

(NH4)42[Mo VI72 Mo V60 O372(CH3COO)30(H2O)72], a Keplerate-type giant nanoporous isopolyoxomolybdate, denoted as ({Mo132}), was found to have extraordinary catalytic activity in the synthesis of 1,8-dioxo-octahydroxanthenes, and 1,8-dioxodecahydroacridines via one-pot reactions. The catalyst was prepared using inexpensive and readily available materials and characterized using FT-IR, and UV spectra. The desired products were obtained only within a few seconds in high yields under solvent-free conditions at 130 °C. Furthermore, the procedures and work-ups were simple and the catalyst can be conveniently recovered and reused. To our knowledge, the catalyst exhibits the highest activity over other procedures available in the literature for the synthesis of the mentioned compounds.

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Acknowledgments

The authors express their gratitude to the Islamic Azad University, Mashhad Branch for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Ahmad Nakhaei, Abolghasem Davoodnia & Ali Morsali

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  1. Ahmad Nakhaei
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  2. Abolghasem Davoodnia
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  3. Ali Morsali
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Correspondence to Abolghasem Davoodnia.

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Nakhaei, A., Davoodnia, A. & Morsali, A. Extraordinary catalytic activity of a Keplerate-type giant nanoporous isopolyoxomolybdate in the synthesis of 1,8-dioxo-octahydroxanthenes and 1,8-dioxodecahydroacridines. Res Chem Intermed 41, 7815–7826 (2015). https://doi.org/10.1007/s11164-014-1861-9

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