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The influence of sodium and barium ions on the structures of iridium (III) acetylacetonate complexes

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Abstract

Two iridium acetylacetonate complexes [Na(H2O)Ir(acac)2Cl2] n (compound 1) and [Ba(H2O)5Ir(acac)2Cl2Ba(H2O)5][Ir(acac)2Cl2]3·2H2O (compound 2) were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, NMR, IR, and absorption spectra. The influence of sodium and barium ions on their molecular structures was explored.

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Acknowledgments

This work was financially supported by the Science and Technology Development Program of National, Yunnan Province and Yunnan Tin Group, P. R. China (2013EG115008, 2012BAE06B08, 2012CF003, and 2012-57A).

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Authors and Affiliations

  1. Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, Yunnan, People’s Republic of China

    Qiaowen Chang & Weiping Liu

  2. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming, 650106, Yunnan, People’s Republic of China

    Qiaowen Chang, Caixian Yan, Hao Cui, Qingsong Ye, Jing Jiang, Juan Yu, Jialin Chen & Weiping Liu

  3. State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming, 650204, Yunnan, People’s Republic of China

    Xiao-Nian Li

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  1. Qiaowen Chang
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  2. Caixian Yan
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  3. Xiao-Nian Li
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  4. Hao Cui
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  5. Qingsong Ye
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  7. Juan Yu
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  8. Jialin Chen
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  9. Weiping Liu
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Correspondence to Weiping Liu.

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Chang, Q., Yan, C., Li, XN. et al. The influence of sodium and barium ions on the structures of iridium (III) acetylacetonate complexes. Res Chem Intermed 41, 7631–7640 (2015). https://doi.org/10.1007/s11164-014-1848-6

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  • DOI: https://doi.org/10.1007/s11164-014-1848-6

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