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Inhibition of mild steel corrosion in sulfuric acid solution using collagen

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Abstract

Inhibitive effect of collagen on the acid corrosion of mild steel in 0.5 M H2SO4 solution was studied by electrochemical impedance spectroscopy and electrochemical frequency modulation. Collagen effectively inhibited the corrosion of mild steel with efficiency ranges from 88.9 to 96.5 % for collagen concentrations from 20 to 80 ppm. Adsorption isotherm study was performed using weight loss measurements where Langmuir and El-Awady models were applied on data to investigate the mode of adsorption. Corrosion inhibition was also tested at different temperatures to measure the thermodynamic parameters; ΔG°, ΔH°, ΔS° and E a. Inhibition is suggested to occur due to adsorption phenomenon and data obey the El-Awady model. Thermodynamic study reveals that adsorption is endothermic–physical process driven by entropic factors.

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Acknowledgments

The authors would like to thank the Egyptian Armed Force for providing access to the testing facilities to undertake this project. Moreover, the authors would also like to thank Prof. Seleet, Military Technical College, Cairo, Egypt, for his invaluable advice during this work.

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  1. Mohamed Gobara

    Present address: Egyptian Armed Force, Kobry Elkobba, Cairo, Egypt

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  1. Egyptian Armed Force, Kobry Elkobba, Cairo, Egypt

    Mohamed Gobara, Ahmad Baraka & Basem Zaghloul

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  1. Mohamed Gobara
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  2. Ahmad Baraka
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Correspondence to Mohamed Gobara.

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Gobara, M., Baraka, A. & Zaghloul, B. Inhibition of mild steel corrosion in sulfuric acid solution using collagen. Res Chem Intermed 41, 7245–7261 (2015). https://doi.org/10.1007/s11164-014-1809-0

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