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Melamine supported on hydroxyapatite-encapsulated-γ-Fe2O3: a novel superparamagnetic recyclable basic nanocatalyst for the synthesis of 1,4-dihydropyridines and polyhydroquinolines

Research on Chemical Intermediates volume 41, pages 7227–7244 (2015)Cite this article

Abstract

In this paper, the preparation and characterization of hydroxyapatite-encapsulated γ-Fe2O3 nanoparticles functionalized with Melamine nanocomposite (γ-Fe2O3@HAp@Melamine) are presented. The resulting nanocomposite was characterized by infrared spectroscopy, scanning electron microscope, thermal gravimetric analysis, X-ray diffraction, vibrating sample magnetometer and elemental analysis. The catalytic activity of γ-Fe2O3@ HAp@Melamine as a magnetic powerful basic nanocatalyst was probed through one-pot synthesis of 1, 4-dihydropyridine and polyhydroquinoline derivatives through Hantzsch condensation reaction under solvent-free thermal conditions. The heterogeneous catalyst could be recovered easily by simple magnetic decantation and reused many times without significant loss of its catalytic activity.

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Acknowledgment

We are grateful to the Research Council of ShahidChamran University for financial support.

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Authors and Affiliations

  1. Chemistry Department, College of Science, ShahidChamran University, 61357-4-3169, Ahvaz, Iran

    Sedighe Igder & Ali Reza Kiasat

  2. Faculty of Chemistry, Jundishapur University of Medical Sciences, Ahvaz, Iran

    Mohamad Reza Shushizadeh

Authors
  1. Sedighe Igder
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  2. Ali Reza Kiasat
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  3. Mohamad Reza Shushizadeh
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Correspondence to Ali Reza Kiasat.

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Igder, S., Kiasat, A.R. & Shushizadeh, M.R. Melamine supported on hydroxyapatite-encapsulated-γ-Fe2O3: a novel superparamagnetic recyclable basic nanocatalyst for the synthesis of 1,4-dihydropyridines and polyhydroquinolines. Res Chem Intermed 41, 7227–7244 (2015). https://doi.org/10.1007/s11164-014-1808-1

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  • DOI: https://doi.org/10.1007/s11164-014-1808-1

Keywords

  • Magnetic basic nanocatalyst
  • Nano γ-Fe2O3 supported Melamine
  • γ-Fe2O3@HAp
  • 1,4-Dihydropyridines
  • Polyhydroquinolines