Skip to main content
SpringerLink
Log in

Inhibition effect of adsorption layer of 1-phenyl-4-(4-nitrophenyl) thiosemicarbazide on the corrosion of 18 Ni 250-grade welded maraging steel in 1.0 M hydrochloric acid medium

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The thiosemicarbazide derivative, 1-phenyl-4-(4-nitrophenyl)thiosemicarbazide (PNPT), was synthesized and its inhibiting action on the corrosion of welded maraging steel in 1.0 M hydrochloric acid was investigated by electrochemical methods of potentiodynamic (Tafel) polarization and electrochemical impedance spectroscopy. The inhibitor, PNPT, acted essentially as a mixed-type inhibitor with predominant cathodic action. The inhibition efficiency increased with the increase in inhibitor concentration. An inhibition efficiency of about 86 % was exhibited at 30 °C, which decreased with the increase in the temperature. The adsorption of the inhibitor layer formed was through predominant physical adsorption process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. ASM handbook, vol. 1. ASM International, Materials Park, OHIO, USA, pp. 1225–1237, 2005

  2. K. Rohrbach, M. Schmidt, ASM Handbook, 10th ed., vol. 1, ASM International, pp. 796, 1990

  3. D.G. Lee, K.C. Jang, J.M. Kuk, I.S. Kim, J. Mater. Process. Technol. 162, 342 (2005)

    Article  Google Scholar 

  4. W.W. Krick, R.A. Covert, T.P. May, Met. Eng. Quart. 8, 31 (1968)

    Google Scholar 

  5. L.W. Tsay, H.H. Chen, M.F. Chiang, C. Chen, Corros. Sci. 49, 2461 (2007)

    Article  CAS  Google Scholar 

  6. J. Rezek, I.E. Klein, J. Yhalom, Corros. Sci. 39, 385 (1999)

    Article  Google Scholar 

  7. C.M. Adama, R.E. Travis, Weld. J. 43, 193 (1964)

    Google Scholar 

  8. B. Gomez, N.V. Likhhanova, M.A. Dominguez-Aguilar, R. Martinez-Palou, A. Vela, J.L. Gazquez, J. Phys. Chem. B 110, 8928 (2006)

    Article  CAS  Google Scholar 

  9. J. Fang, J.J. Li, Mol. Struct. 593, 179 (2002)

    Article  CAS  Google Scholar 

  10. G. Schmitt, Br. Corros. J. 19, 165 (1984)

    Article  CAS  Google Scholar 

  11. S. Tamil Selvi, V. Raman, N. Rajendran, J. Appl. Electrochem. 33, 1175 (2003)

    Article  CAS  Google Scholar 

  12. B.S. Sanatkumar, J. Nayak, A.N. Shetty, J. Coat. Technol. Res. 9, 483 (2012)

    Article  CAS  Google Scholar 

  13. B.S. Sanatkumar, J. Nayak, A.N. Shetty, Int. J. Hydrogen Energy 37, 9431 (2012)

    Article  CAS  Google Scholar 

  14. M.M. Britto, T.M.G. Almeida, A. Leitão, C.L. Donnici, M.T.P. Lopes, C.A. Montanari, Int. J. Rapid Commun. Synth. Org. Chem. 36, 3359 (2006)

    CAS  Google Scholar 

  15. S.W. Dean, Norm ASTM G102, Standard practice for calculation of corrosion rates and related information from electrochemical measurements, 1999

  16. R.A. Prabhu, A.V. Shanbhag, T.V. Venkatesha, J. Appl. Electrochem. 37, 491 (2007)

    Article  CAS  Google Scholar 

  17. A.M. Fekry, M.A. Ameer, Int. J. Hydrogen Energy 35, 7641 (2010)

    Article  CAS  Google Scholar 

  18. D. Jayaperumal, Mater. Chem. Phys. 119, 478 (2010)

    Article  CAS  Google Scholar 

  19. W. Li, Q. He, S. Zhang, C. Pei, B. Hou, J. Appl. Electrochem. 38, 289 (2008)

    Article  CAS  Google Scholar 

  20. F. Touhami, A. Aouniti, Y. Abed, B. Hammouti, S. Kertit, A. Ramdani, K. Elkacemi, Corros. Sci. 42, 929 (2000)

    Article  CAS  Google Scholar 

  21. Q.B. Zhang, Y.X. Hua, Electrochim. Acta 54, 1881 (2009)

    Article  CAS  Google Scholar 

  22. R. Solmaz, Corros. Sci. 81, 75 (2014)

    Article  CAS  Google Scholar 

  23. S. John, A. Joseph, Mater. Chem. Phys. 133, 1083 (2012)

    Article  CAS  Google Scholar 

  24. T. Ghailane, R.A. Balkhmima, R. Ghailane, A. Souizi, R. Touir, M. Ebn Touhami, K. Marakchi, N. Komiha, Corros. Sci. 76, 317 (2013)

    Article  CAS  Google Scholar 

  25. M.A. Veloz, I. Gonzalez, Electrochim. Acta 48, 135 (2002)

    Article  CAS  Google Scholar 

  26. T. Poornima, J. Nayak, A.N. Shetty, J. Appl. Electrochem. 41, 223 (2011)

    Article  CAS  Google Scholar 

  27. I. Ahamad, R. Prasad, M.A. Quraishi, Corros. Sci. 52, 1472 (2010)

    Article  CAS  Google Scholar 

  28. E. Machnikova, H. Kenton Whitmire, N. Hackerman, Electrochim. Acta 53, 6024 (2008)

    Article  CAS  Google Scholar 

  29. R. Solmaz, Corros. Sci. 79, 169 (2014)

    Article  CAS  Google Scholar 

  30. S. Srinivasan, Electrode/electrolyte interfaces: Structure and kinetics of charge transfer. Fuel cells: from fundamentals to applications, (Springer, New York, 2006), p. 28

  31. M.P. Geetha, J. Nayak, A.N. Shetty, Mater. Chem. Phys. 125, 628 (2011)

    Article  Google Scholar 

  32. F. Bentiss, M. Lebrini, M. Lagrenee, Corros. Sci. 47, 2915 (2005)

    Article  CAS  Google Scholar 

  33. G. Avci, Colloids Surf. A 317, 730 (2008)

    Article  CAS  Google Scholar 

  34. A.S. Fouda, F.E. Heakal, M.S. Radwan, J. Appl. Electrochem. 39, 391 (2009)

    Article  CAS  Google Scholar 

  35. R.F.V. Villamil, P. Corio, S.M.L. Agostinho, J.C. Rubin, J. Electroanal. Chem. 472, 112 (1999)

    Article  CAS  Google Scholar 

  36. G. Moretti, G. Quartarone, A. Tassan, A. Zingales, Mater. Corros. 45, 641 (1994)

    Article  CAS  Google Scholar 

  37. Z. Tao, S. Zhang, W. Li, B. Hou, Ind. Eng. Chem. Res. 49, 2593 (2010)

    Article  CAS  Google Scholar 

  38. T. Poornima, J. Nayak, A.N. Shetty, Corros. Sci. 53, 3688 (2011)

    Article  CAS  Google Scholar 

  39. G.R. Fuchs, Colloids Surf. A 280, 130 (2006)

    Article  Google Scholar 

  40. M. Hosseini, S.F.L. Mertens, M.R. Arshadi, Corros. Sci. 45, 1473 (2003)

    Article  CAS  Google Scholar 

  41. S. Ashish Kumar, M.A. Quraishi, Corros. Sci. 52, 152 (2010)

    Article  Google Scholar 

  42. N. Hackerman, E.S. Snavely, J.S. Payne Jr, J. Electrochem. Soc. 113, 677 (1966)

    Article  CAS  Google Scholar 

  43. A.K. Satpati, P.V. Ravindran, Mater. Chem. Phys. 109, 352 (2008)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, National Institute of Technology Karnataka, Srinivasnagar, Surathkal, 575 025, Karnataka, India

    Pradeep Kumar & A. Nityananda Shetty

Authors
  1. Pradeep Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Nityananda Shetty
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Nityananda Shetty.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, P., Nityananda Shetty, A. Inhibition effect of adsorption layer of 1-phenyl-4-(4-nitrophenyl) thiosemicarbazide on the corrosion of 18 Ni 250-grade welded maraging steel in 1.0 M hydrochloric acid medium. Res Chem Intermed 41, 7095–7113 (2015). https://doi.org/10.1007/s11164-014-1800-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-014-1800-9

Keywords

Search

Navigation