Skip to main content
Log in

The extract of Jamun (Syzygium cumini) seed as green corrosion inhibitor for acid media

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The corrosion inhibition of mild steel in hydrochloric acid and sulfuric acid solutions by the extract of Syzygium cumini seed was studied using chemical, electrochemical impedance spectroscopy, linear polarization, and potentiodynamic polarization techniques. The inhibition was assumed to occur via adsorption of the inhibitor molecules on the metal surface. The adsorption of the extract on the mild steel surface obeyed Langmuir’s isotherm. The results obtained showed that the extract of S. cumini could act as an effective inhibitor of the corrosion of mild steel in hydrochloric and sulfuric acid media.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. H. Ashassi-Sorkhabi, D. Seifzadeh, M.G. Hosseini, Corros. Sci. 50, 3363–3370 (2008)

    Article  CAS  Google Scholar 

  2. A.K. Satapathy, G. Gunasekaran, S.C. Sahoo, A. Kumar, P.V. Rodrigues, Corros. Sci. 51, 2848–2856 (2009)

    Article  CAS  Google Scholar 

  3. A.M. Abdel-Gaber, B.A. Abd-El-Nabey, M. Saadawy, Corros. Sci. 51, 1038–1042 (2009)

    Article  CAS  Google Scholar 

  4. P.B. Raja, M.G. Sethuraman, Mater. Lett. 62, 113–116 (2008)

    Article  CAS  Google Scholar 

  5. E.A. Noor, J. Engg. Appl. Sci. 3, 23–30 (2008)

    CAS  Google Scholar 

  6. J. Buchweishaija, G.S. Mhinzi, Port. Electrochim. Acta 26, 257–265 (2008)

    Article  CAS  Google Scholar 

  7. E.E. Oguzie, Corros. Sci. 50, 2993–2998 (2008)

    Article  CAS  Google Scholar 

  8. P.C. Okafor, M.E. Ikpi, I.E. Uwaha, E.E. Ebenso, U.J. Ekpe, S.A. Umoren, Corros. Sci. 50, 2310–2317 (2008)

    Article  CAS  Google Scholar 

  9. L. Valek, S. Martinez, Mater. Lett. 61, 148–151 (2007)

    Article  CAS  Google Scholar 

  10. O. Avwiri Gregory, F.O. Igho, Mater. Lett. 57, 3705–3711 (2003)

    Article  Google Scholar 

  11. O.K. Orubite, N.C. Oforka, J. Appl. Sci. Environ. Manag. 8, 57–61 (2004)

    Google Scholar 

  12. E.A. Noor, J. Appl. Electrochem. 39, 1465–1475 (2009)

    Article  CAS  Google Scholar 

  13. F.S. De Souza, A. Spinelli, Corros. Sci. 51, 642–649 (2009)

    Article  Google Scholar 

  14. A.Y. El-Etre, Corros. Sci. 45, 2485–2495 (2003)

    Article  CAS  Google Scholar 

  15. A.M. Badiea, K.N. Mohana, J. Mater. Eng. Perform. 18, 1264–1271 (2009)

    Article  CAS  Google Scholar 

  16. M. Lebrini, F. Robert, A. Lecante, C. Roos, Corros. Sci. 53, 687–695 (2011)

    Article  CAS  Google Scholar 

  17. A. Singh, V.K. Singh, M.A. Quraishi, Rasayan J. Chem. 3, 811–824 (2010)

    CAS  Google Scholar 

  18. A. Singh, I. Ahamad, V.K. Singh, M.A. Quraishi, Chem. Eng. Commun. 199, 63–77 (2012)

    Article  CAS  Google Scholar 

  19. M.A. Quraishi, A. Singh, V.K. Singh, D.K. Yadav, A.K. Singh, Mater. Chem. Phys. 122, 114–122 (2010)

    Article  CAS  Google Scholar 

  20. A. Singh, I. Ahamad, V.K. Singh, M.A. Quraishi, J. Solid State Electrochem. 15, 1087–1097 (2011)

    Article  CAS  Google Scholar 

  21. A. Singh, V.K. Singh, M.A. Quraishi, International J. Corros. IJC/27598 (2010)

  22. A. Singh, V.K. Singh, M.A. Quraishi, J. Mater. Environ. Sci. 1, 162–174 (2010)

    Google Scholar 

  23. A. Singh, M.A. Quraishi, Int. J. Electrochem. Sci. 7, 3409–3419 (2012)

    CAS  Google Scholar 

  24. P.S.M. Prince, N. Kamalakkannan, V.P. Menon, J. Ethnopharmacol. 84, 205–209 (2003)

    Article  Google Scholar 

  25. G. Mars Fontana, Corrosion engineering (Mcgrawhill, Singapore, 1987), p. 173

    Google Scholar 

  26. Ishtiaque. Ahamad, M.A. Quraishi, Corros. Sci. 52, 651–656 (2010)

    Article  CAS  Google Scholar 

  27. M. Schorr, J. Yahalom, Corros. Sci. 12, 867–868 (1972)

    Article  CAS  Google Scholar 

  28. Ishtiaque. Ahamad, Rajendra. Prasad, M.A. Quraishi, Corros. Sci. 52, 3033–3041 (2010)

    Article  CAS  Google Scholar 

  29. Ishtiaque. Ahamad, Rajendra. Prasad, M.A. Quraishi, Corros. Sci. 52, 1472–1481 (2010)

    Article  CAS  Google Scholar 

  30. I.N. Putilova, S.A. Balezin, U.P. Baranik, Metallic corrosion inhibitor (Pergamon, New York, 1960), p. 31

    Google Scholar 

  31. E. Khamis, A. Hosney, S. El-Khodary, Afinidad 52, 95–101 (1995)

    CAS  Google Scholar 

  32. M. Elayyachy, A. El Idrissi, B. Hammouti, Corros. Sci. 48, 2470–2479 (2006)

    Article  CAS  Google Scholar 

  33. S. Martinez, M. Metikos-Hukovic, J. Appl. Electrochem. 33, 1137–1142 (2003)

    Article  CAS  Google Scholar 

  34. F. Mansfeld, Corrosion 36, 301–307 (1981)

    Article  Google Scholar 

  35. M. Hosseini, S.F.L. Mertens, M. Ghorbani, M.R. Arshadi, Mater. Chem. Phys. 78, 800–808 (2003)

    Article  CAS  Google Scholar 

  36. A.K. Singh, M.A. Quraishi, Mater. Chem. Phys. 123, 666–677 (2010)

    Article  CAS  Google Scholar 

  37. J. Shukla, K.S. Pitre, Corros. Rev. 20, 217–229 (2002)

    CAS  Google Scholar 

  38. M. Mahdavian, A.A. Attar, Corros. Sci. 51, 409–414 (2009)

    Article  CAS  Google Scholar 

  39. I. Ahamad, C. Gupta, R. Prasad, M.A. Quraishi, J. Appl. Electrochem. 40, 2171–2183 (2010)

    Article  CAS  Google Scholar 

  40. M.S. Morad, A.M. Kamal El dean, Corros. Sci. 48, 3398–3412 (2006)

    Article  CAS  Google Scholar 

  41. G.K. Gomma, M.H. Wahdan, Mater. Chem. Phys. 39, 142–148 (1994)

    Article  CAS  Google Scholar 

  42. A.K. Singh, M.A. Quraishi, J. Appl. Electrochem. 40, 1293–1306 (2010)

    Article  CAS  Google Scholar 

  43. Ishtiaque. Ahamad, Rajendra. Prasad, M.A. Quraishi, J. Solid State Electrochem. 14, 2095–2105 (2010)

    Article  CAS  Google Scholar 

  44. I.S. Bhatia, K.L. Bajaj, Biochem. J. 128, 56 (1972)

    Google Scholar 

  45. G. Trabenelli, F. Mansfeld, Corrosion mechanisms (Marcel Dekker, New York, 1987), p. 109

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Quraishi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Singh, A., Quraishi, M.A. The extract of Jamun (Syzygium cumini) seed as green corrosion inhibitor for acid media. Res Chem Intermed 41, 2901–2914 (2015). https://doi.org/10.1007/s11164-013-1398-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-013-1398-3

Keywords

Navigation