Abstract
An acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the condensation reaction of 2,6-diformyl-4-ter-butylphenol and 4-aminoantipyrine. The synthesized ligand and complexes of the metal ions [CrIII, FeIII, CoII,NiII,CuII and ZnII] were characterized by 1HNMR, 13CNMR, mass spectrometry, UV/visible, FTIR, atomic absorption, elemental analysis (C.H.N.), molar conductivitym and magnetic susceptibility measurements. A binuclear complex was obtained through phenolic oxygen acting as a bridge between two metal ions.
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Abid, K.K., Omar, AA.B. Synthesis and spectroscopic studies of dinuclear Schiff base and its transition metal complexes with Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) ions. Res Chem Intermed 41, 1715–1726 (2015). https://doi.org/10.1007/s11164-013-1306-x
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DOI: https://doi.org/10.1007/s11164-013-1306-x