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Modified wool as adsorbent for the removal of Cr(III) from aqueous solution: adsorption properties, isotherm and kinetics

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Abstract

Waste wool was modified by maleic anhydride, and modified wool was prepared by optimizing the conditions such as pH, temperature, and time. The adsorption isotherm, as well as the kinetics of the modified wool, were studied. The results showed that modified wool was effective in removing Cr(III) in wastewater. The maximum adsorption was reached when the pH was about 4.5, the time was 120 min, and the temperature was 30 °C. The experimental results were fitted using Langmuir and Freundlich equations. The results indicate that the Langmuir isotherm is better at describing the adsorption process. Two kinetic models, the pseudo-first-order and pseudo-second-order, were used for analyzing the kinetic data, and the latter was shown to describe the adsorption behavior better.

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References

  1. A. Maggie, Water and sanitation in developing countries: including health in the equation. Montgomery, Menachem Elimelech. Environ. Sci. Technol. 41, 17–24 (2007)

    Article  Google Scholar 

  2. M.A. Abreu, S.M. Toffoli, Characterization of a chromium-rich tannery waste and its potential use in ceramics. Ceram. Int. 35, 2225–2234 (2009)

    Article  CAS  Google Scholar 

  3. C. Fabiani, F. Ruscio, M. Spadoni, Chromium(III) salts recovery process from tannery wastewaters. Desalination 108, 183–191 (1997)

    Article  CAS  Google Scholar 

  4. V.J. Sundar, J. Raghava Rao, C. Muralidharan, Cleaner chrome tanning-emerging options. J. Clean. Prod. 10, 69–74 (2002)

    Article  Google Scholar 

  5. T. Basegio, F. Berutti, A. Bernardes, Environmental and technical aspects of the utilisation of tannery sludge as a raw material for clay products. J. European Ceram. Soc. 22, 2251–2259 (2002)

    Article  CAS  Google Scholar 

  6. D. Mohan, C. U. Pittman Jr., Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water. J. Hazard. Mater. 137, 762–811 (2006)

    Article  CAS  Google Scholar 

  7. L. Sirajuddin, G.L. Kakakhel, Electrolytic recovery of chromium salts from tannery wastewater. J. Hazard. Mater. 148, 560–565 (2007)

    Article  CAS  Google Scholar 

  8. Z. Song, C.J. Williams, R.G.J. Edyvean, Sedimentation of tannery wastewater. Water Res. 34, 2171–2176 (2000)

    Article  CAS  Google Scholar 

  9. A. Cassano, R. Molinari, E. Drioli, Saving of water and chemicals in tanning industry by membrane processes. Water Sci. Technol. 40, 443–450 (1999)

    Article  CAS  Google Scholar 

  10. I. Martin, M. Pidou, A. Soares, Modelling the energy demands of aerobic and anaerobic membrane bioreactors for wastewater treatment. Environ. Technol. 32, 921–932 (2011)

    Article  CAS  Google Scholar 

  11. L.-H. Wang, C.-I. Lin, Equilibrium study on chromium(III) ion removal by adsorption onto rice hull ash. J. Taiwan Inst. Chem. E. 40, 110–112 (2009)

    Article  CAS  Google Scholar 

  12. A. Shukla, Y.-H. Zhang, The role of sawdust in the removal of unwanted materials from water. P. Dubey. J. Hazard. Mater. 95, 137–152 (2002)

    Article  CAS  Google Scholar 

  13. K.L. Wasewar, M. Atif, B. Prasad, Batch Adsorption of zinc on tea factory waste. Desalination 244, 66–71 (2009)

    Article  CAS  Google Scholar 

  14. E. Malkoc, Y. Nuhoglu, Investigation of nickel(II) removal from aqueous solutions using tea factory waste. J. Hazard. Mater. 127, 120–128 (2005)

    Article  CAS  Google Scholar 

  15. U.K. Garg, M.P. Kaur, V.K. Garg, Removal of hexavalent chromium from aqueous solution by agricultural waste biomass. Garg. J. Hazard. Mater. 140, 60–68 (2007)

    Article  CAS  Google Scholar 

  16. T.K. Chaithanya, Y. Sudhakar, Adsorption of hexa-valent chromium using treated wood charcoal-elucidation of rate-limiting process. Environ. Technol. 31, 1495–1505 (2010)

    Article  CAS  Google Scholar 

  17. A. Bhatnagar, V.J.P. Vilar, M.S. Cidalia, A Review of the use of red mud as adsorbent for the removal of toxic pollutants from water and wastewater. Botelho. Environ. Technol. 32, 231–249 (2011)

    Article  CAS  Google Scholar 

  18. R. Dhankhar, A. Hooda, Fungal biosorption-an alternative to meet the challenges of heavy metal pollution in aqueous solution. Environ. Technol. 32, 467–491 (2011)

    Article  CAS  Google Scholar 

  19. V. Orescanin, R. Kollar, D. Ruk, Characterization and electrochemical treatment of landfill leachate. J. Environ. Sci. Health-Part A 47, 462–469 (2012)

    Article  CAS  Google Scholar 

  20. S. Renou, J.G. Givaudan, S. Poulain, Landfill leachate treatment: review and opportunity. J. Hazard. Mater. 150, 468–493 (2008)

    Article  CAS  Google Scholar 

  21. J. Li, Q. Lin, X. Zhang, Kinetic parameters and mechanisms of the batch biosorption of Cr(VI) and Cr(III) onto Leersia hexandra Swartz biomass. J. Colloid Interface Sci. 333, 71–77 (2009)

    Article  CAS  Google Scholar 

  22. T. Yilmaz, A. Aygun, A. Berktay, Removal of COD and colour from young municipal landfill leachate by Fenton process. Environ. Technol. 31, 1635–1640 (2010)

    Article  CAS  Google Scholar 

  23. M. Saleem, T. Pirzada, R. Qadeer, Sorption of some azo-dyes on wool fiber from aqueous solutions. Colloids Surf. A 260, 183–188 (2005)

    Article  CAS  Google Scholar 

  24. G. Freddi, T. Arai, G.M. Colonna, Binding of metal cations to chemically modified wool and antimicrobial properties of the wool-metal complexes. J. Appl. Polym. Sci. 82, 3513–3519 (2001)

    Article  CAS  Google Scholar 

  25. X. Wang, X. Shen, X. Weilin, Effect of hydrogen peroxide treatment on the properties of wool fabric. Appl. Surf. Sci. 258, 10012–10016 (2012)

    Article  CAS  Google Scholar 

  26. L.M. Pandey, S.K. Pattanayek, Hybrid surface from self-assembled layer and its effect on protein adsorption. Appl. Surf. Sci. 257, 4731–4737 (2011)

    Article  CAS  Google Scholar 

  27. J. Peng, H. Xia, M. Zhai, Radiation-induced graft polymerization of maleic acid and maleic anhydride onto ultra-fine powdered styrene-butadiene rubber (UFSBR). Radiat. Phys. Chem. 76, 1741–1745 (2007)

    Article  CAS  Google Scholar 

  28. T. Budinova, D. Savona, B. Tsyntsarski, Biomass waste-derived activated carbon for the removal of arsenic and manganese ions from aqueous solutions. Appl. Surf. Sci. 225, 4650–4657 (2009)

    Article  Google Scholar 

  29. A. Adbel-Nasser, EI-Hendawy, Surface and adsorptive properties of carbons prepared from biomass. Appl. Surf. Sci. 252, 287–295 (2005)

    Article  Google Scholar 

  30. M.S.U. Rehman, I. Kim, J.-I. Han, Adsorption of methylene blue dye from aqueous solution by sugar extracted spent rice biomass. Carbohyd. Polym. 90, 1314–1322 (2012)

    Article  CAS  Google Scholar 

  31. M. Monier, D.M. Ayad, A.A. Sarhan, Adsorption of Cu(II), Hg(II), and Ni(II) ions by modified natural wool chelating fibers. J. Hazard. Mater. 176, 348–355 (2010)

    Article  CAS  Google Scholar 

  32. Y. Dan, W. Wang, W. Jianwen, Preparation of conductive wool fabrics and adsorption behaviour of Pd (II) ions on chitosan in the pre-treatment. Synth. Met. 161, 124–131 (2011)

    Article  Google Scholar 

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Acknowledgments

This paper was supported by Shaanxi University of Science and Technology Startup Science Research fund (No. BJ09-12), and the Graduate Innovation Fund of Shaanxi University of Science and Technology.

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Correspondence to Wenxin Li.

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Li, W., Ye, Y. Modified wool as adsorbent for the removal of Cr(III) from aqueous solution: adsorption properties, isotherm and kinetics. Res Chem Intermed 41, 803–812 (2015). https://doi.org/10.1007/s11164-013-1232-y

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  • DOI: https://doi.org/10.1007/s11164-013-1232-y

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